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Bruice 8th EditionCh. 10 - Reactions of Alcohols, Ethers, Epoxides, Amines, and Sulfur-Containing Compounds문제 50c,d
Using an alkyl halide and a thiol as starting materials, how would you prepare the following thioethers?
c.
d.
문제 51
The following three nitrogen mustards were studied for possible clinical use. One is now used clinically, one was found to be too unreactive, and one was found to be too insoluble in water to be injected intravenously. Which is which? (Hint: Draw resonance contributors.)
문제 52
Why is melphalan a good cancer drug?
문제 55a
What is the product of each of the following reactions?
a.
문제 55c,d
What is the product of each of the following reactions?
c.
d.
문제 55g
What is the product of each of the following reactions?
g.
문제 56a,b
Indicate which alcohol in each pair undergoes an elimination reaction more rapidly when heated with H2SO4.
a.
b.
문제 56c
Indicate which alcohol in each pair undergoes an elimination reaction more rapidly when heated with H2SO4.
c.
문제 56d
Indicate which alcohol in each pair undergoes an elimination reaction more rapidly when heated with H2SO4.
d.
문제 56e
Indicate which alcohol in each pair undergoes an elimination reaction more rapidly when heated with H2SO4.
e.
문제 57
Identify A–E.
문제 57a(9)
a. Show the reagents required to form the primary alcohol in each of the following reactions.
문제 58a
Starting with (R)-1-deuterio-1-propanol, how could you prepare
a. (S)-1-deuterio-1-propanol?
문제 58b
Starting with (R)-1-deuterio-1-propanol, how could you prepare
b. (S)-1-deuterio-1-methoxypropane?
문제 58c
Starting with (R)-1-deuterio-1-propanol, how could you prepare
c. (R)-1-deuterio-1-methoxypropane?
문제 59a
When heated with H2SO4, both 3,3-dimethyl-2-butanol and 2,3-dimethyl-2-butanol are dehydrated to form 2,3-dimethyl-2-butene. Which alcohol dehydrates more rapidly?
문제 60a,b
What is the major product obtained from the reaction of 2-ethyloxirane with each of the following reagents?
a. 0.1MHCl
b. CH3OH/HCl
문제 60c
What is the major product obtained from the reaction of 2-ethyloxirane with each of the following reagents?
c. 0.1MNaOH
문제 60d
What is the major product obtained from the reaction of 2-ethyloxirane with each of the following reagents?
d. CH3OH/CH3O-
문제 61a
Write the appropriate reagent over each arrow.
문제 61b
Write the appropriate reagent over each arrow.
문제 61c
Write the appropriate reagent over each arrow.
문제 61d
Write the appropriate reagent over each arrow.
문제 61e
Write the appropriate reagent over each arrow.
문제 61f
Write the appropriate reagent over each arrow.
문제 62
What alkenes would you expect to be obtained from the acid-catalyzed dehydration of 1-hexanol?
문제 63a,b
What is the major product(s) of each of the following reactions?
a.
b.
문제 63c
What is the major product(s) of each of the following reactions?
c.
문제 63d
What is the major product(s) of each of the following reactions?
d.
문제 63g
What is the major product(s) of each of the following reactions?
g.
