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Ch. 19 - Amines
Wade - Organic Chemistry 9th Edition
Wade9th EditionOrganic ChemistryISBN: 9780135213728당신이 사용하는 게 아니라요?교과서 변경
19장, 문제 3a,b,c

Give correct names for the following amines:
(a)
(b)
(c)

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Step 1: Identify the parent chain in each amine structure. The parent chain is the longest continuous carbon chain that contains the amine group (-NH2).
Step 2: Number the parent chain starting from the end closest to the amine group to give the amine the lowest possible locant (position number).
Step 3: Name the parent chain as an alkane, replacing the '-e' at the end of the alkane name with '-amine' to indicate the presence of the amine group. For example, methane becomes methanamine.
Step 4: If there are substituents (e.g., alkyl groups or other functional groups) attached to the parent chain, name and number them as prefixes, arranging them alphabetically in the final name.
Step 5: For secondary or tertiary amines (amines with two or three alkyl groups attached to the nitrogen), use the 'N-' prefix to indicate substituents directly attached to the nitrogen atom. For example, N-methylpropanamine indicates a methyl group attached to the nitrogen of a propanamine.

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주요 개념

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Amines

Amines are organic compounds derived from ammonia (NH3) by replacing one or more hydrogen atoms with alkyl or aryl groups. They can be classified as primary, secondary, or tertiary based on the number of carbon-containing groups attached to the nitrogen atom. Understanding the structure of amines is crucial for naming them correctly.
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Reductive Amination

IUPAC Nomenclature

The International Union of Pure and Applied Chemistry (IUPAC) provides a systematic method for naming chemical compounds. For amines, the naming convention involves identifying the longest carbon chain attached to the nitrogen and using suffixes and prefixes to denote the presence of the amine functional group. Familiarity with these rules is essential for accurately naming amines.
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가이드 코스
03:43
The different parts of an IUPAC name

Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. In the case of amines, the amino group (-NH2) is the functional group that defines their reactivity and properties. Recognizing functional groups is vital for understanding how to name and classify organic compounds.
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가이드 코스
02:36
Identifying Functional Groups