Textbook Question
Identify the peaks in the mass spectrum of octan-4-one that correspond to (a) α-cleavage.
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Mullins 1st Edition
Ch. 14 - Structural Identification I: Infrared Spectroscopy and Mass Spectrometry
Problem 45
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Identify the peaks in the mass spectrum of octan-4-one that correspond to (a) α-cleavage.
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Identify the peaks in the mass spectrum of octan-4-one that correspond to (b) the McLafferty rearrangement.
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Based on Hooke's law, choose the bond in each pair that you expect to vibrate at a higher wavenumber.
(f) C―S vs C=O
Based on Hooke's law, choose the bond in each pair that you expect to vibrate at a higher wavenumber.
(e) C=N vs C≡N
2-Methylnonan-4-one can undergo two different McLafferty rearrangements. Draw the products of each of them.
Choose the bond in each pair that you expect to have the more intense stretching band
(b) C=O vs. C=N