Ch.22 - Chemistry of the Nonmetals
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- Complete the exercises below. Explain the following observations: a. For a given oxidation state, the acid strength of the oxyacid in aqueous solution decreases in the order chlorine > bromine > iodine. b. Hydrofluoric acid cannot be stored in glass bottles. c. HI cannot be prepared by treating NaI with sulfuric acid. d. The interhalogen ICl₃ is known, but BrCl₃ is not.
문제 36
문제 37b,e
Write balanced equations for each of the following reactions.
b. When copper(II) nitrate is heated strongly, it decomposes to form copper(II) oxide, nitrogen dioxide, and oxygen.
e. Potassium peroxide reacts with CO2(g) to give potassium carbonate and O2.
- Complete the exercises below. Complete and balance the following equation: c. Na₂O₂ (s) + H₂O (l) →
문제 38
- Complete the exercises below. Complete and balance the following equations: b. Al₂O₃ (s) + H⁺ (aq) →
문제 38
- Complete the exercises below. Predict whether each of the following oxides is acidic, basic, amphoteric, or neutral: a. NO₂, b. CO₂, c. Al₂O₃, d. CaO.
문제 39
- Complete the exercises below. Write the chemical formula for each of the following compounds, and indicate the oxidation state of the group 6A element in each: a. selenous acid, b. potassium hydrogen sulfite, c. hydrogen telluride, d. carbon disulfide, e. calcium sulfate, f. cadmium sulfide, g. zinc telluride.
문제 41
- Complete the exercises below. Write the chemical formula for each of the following compounds, and indicate the oxidation state of the group 6A element in each: a. sulfur tetrachloride, b. selenium trioxide, c. sodium thiosulfate, d. hydrogen sulfide, e. sulfuric acid, f. sulfur dioxide, g. mercury telluride.
문제 42
- Complete the exercises below. In aqueous solution, hydrogen sulfide reduces dilute HNO₃ to NO₂. In all cases, under appropriate conditions, the product is elemental sulfur. Write a balanced net ionic equation for each reaction.
문제 43
- Complete the exercises below. An aqueous solution of SO₂ reduces a. aqueous KMnO₄ to MnSO₄ (aq) b. acidic aqueous K₂Cr₂O₇ to aqueous Cr⁵⁺, c. aqueous Hg₂(NO₃)₂ to mercury metal. Write balanced equations for these reactions.
문제 44
- Complete the exercises below. Write the Lewis structure for each of the following species, and indicate the structure of each: a. SeO₃²⁻; b. S₂Cl₂; c. chlorosulfonic acid, HSO₃Cl (chlorine is bonded to sulfur).
문제 45
- Complete the exercises below. The SF₅⁻ ion is formed when SF₄ (g) reacts with fluoride salts containing large cations, such as CsF(s). Draw the Lewis structures for SF₄ and SF₅⁻, and predict the molecular structure of each.
문제 46
- Complete the exercises below. Write a balanced equation for each of the following reactions: a. Sulfur dioxide reacts with water. b. Solid zinc sulfide reacts with hydrochloric acid. c. Elemental sulfur reacts with sulfite ion to form thiosulfate. d. Sulfur trioxide is dissolved in sulfuric acid.
문제 47
- Complete the exercises below. Write a balanced equation for each of the following reactions. a. Hydrogen selenide can be prepared by the reaction of an aqueous acid solution on aluminum selenide. b. Sodium thiosulfate is used to remove excess Cl₂ from chlorine-bleached fabrics. The thiosulfate ion forms SO₄²⁻ and elemental sulfur, while Cl₂ is reduced to Cl⁻.
문제 48
- Complete the exercises below. Write the chemical formula for each of the following compounds, and indicate the oxidation state of nitrogen in each: a. sodium nitrite, b. ammonia, c. nitrous oxide, d. sodium cyanide, e. nitric acid, f. nitrogen dioxide, g. nitrogen, h. boron nitride.
문제 49
- Complete the exercises below. Write the Lewis structure for each of the following species, describe its geometry, and indicate the oxidation state of the nitrogen: a. HNO₂, b. N₃⁻, c. N₂H₅⁺, d. NO₃⁻.
문제 51
- Complete the exercises below. Write the Lewis structure for each of the following species, describe its geometry, and indicate the oxidation state of the nitrogen: a. NH₄⁺, b. NO₂⁻, c. N₂O, d. NO₂.
문제 52
- Complete the exercises below. Complete and balance the following equations: a. Mg₃N₂ (s) + H₂O (l) → Which ones of these are redox reactions?
문제 53
- Complete the exercises below. Write a balanced net ionic equation for each of the following reactions: a. Dilute nitric acid reacts with zinc metal with formation of nitrous oxide. b. Concentrated nitric acid reacts with sulfur with formation of nitrogen dioxide. c. Concentrated nitric acid oxidizes sulfur dioxide with formation of nitric oxide. d. Hydrazine is burned in excess fluorine gas, forming NF₃. e. Hydrazine reduces CrO₄²⁻ to Cr(OH)₄⁻ in base (hydrazine is oxidized to N₂).
문제 54
- Complete the exercises below. Write complete balanced half-reactions for: a. oxidation of nitrous acid to nitrate ion in acidic solution, b. oxidation of N₂ to N₂O in acidic solution.
문제 55
- Complete the exercises below. Write complete balanced half-reactions for: a. reduction of nitrate ion to NO in acidic solution, b. oxidation of HNO₂ to NO₂ in acidic solution.
문제 56
- Complete the exercises below. Write a molecular formula for each compound, and indicate the oxidation state of the group 5A element in each formula: a. phosphorous acid, b. pyrophosphoric acid, c. antimony trichloride, d. magnesium arsenide, e. diphosphorus pentoxide, f. sodium phosphate.
문제 57
- Complete the exercises below. Write a chemical formula for each compound or ion, and indicate the oxidation state of the group 5A element in each formula: a. phosphate ion, b. arsenous acid, c. antimony(III) sulfide.
문제 58
- Complete the exercises below. Account for the following observations: a. Phosphorus forms a pentachloride, but nitrogen does not. b. H₃PO₂ is a monoprotic acid. c. Phosphonium salts, such as PH₄Cl, can be formed under anhydrous conditions, but they cannot be made in aqueous solution. d. White phosphorus is more reactive than red phosphorus.
문제 59
- Complete the exercises below. Write a balanced equation for each of the following reactions: a. preparation of white phosphorus from calcium phosphate, b. hydrolysis of PBr₃, c. reduction of PBr₃ to P₄ in the gas phase, using H₂.
문제 61
- Complete the exercises below. Write a balanced equation for each of the following reactions: a. hydrolysis of PCl₅ b. dehydration of phosphoric acid (also called orthophosphoric acid) to form pyrophosphoric acid.
문제 62
- Complete the exercises below. Give the chemical formula for: a. hydrocyanic acid, b. nickel tetracarbonyl, c. barium bicarbonate, d. calcium acetylide, e. potassium carbonate.
문제 63
- Complete the exercises below. Give the chemical formula for: a. carbonic acid, b. sodium cyanide, c. potassium hydrogen carbonate, d. acetylene, e. iron pentacarbonyl.
문제 64
- Complete the exercises below. Complete and balance the following equations: e. Ca(CN)₂ (s) + HBr (aq) → ?
문제 65
- Complete the exercises below. Complete and balance the following equations: b. NaHCO₃ (g) + H⁺ (aq) →
문제 66
- Complete the exercises below. Write a balanced equation for each of the following reactions: a. Hydrogen cyanide is formed commercially by passing a mixture of methane, ammonia, and air over a catalyst at 800 °C. Water is a by-product of the reaction. b. Baking soda reacts with acids to produce carbon dioxide gas. c. When barium carbonate reacts in air with sulfur dioxide, barium sulfate and carbon dioxide form.
문제 67