What alkene would you start with if you wanted to synthesize

b. ethylcyclopentane?

How many different alkenes can be hydrogenated to form

a. butane?

b. 3-methylpentane?

The same alkane is obtained from the catalytic hydrogenation of both alkene A and alkene B. The heat of hydrogenation of alkene A is 29.8 kcal/mol, and the heat of hydrogenation of alkene B is 31.4 kcal/mol. Which alkene is more stable?

Rank the following compounds from most stable to least stable:

trans-3-hexene, cis-3-hexene, cis-2,5-dimethyl-3-hexene, (Z)-3,4-dimethyl-3-hexene

Convert the following perspective formulas to Fischer projections.

(c)

(d)

Draw a reaction coordinate diagram for a reaction in which

a. the product is thermodynamically unstable and kinetically unstable.

b. the product is thermodynamically unstable and kinetically stable.

The rate of the reaction of methyl chloride with hydroxide ion is linearly dependent on both the concentration of methyl chloride and the concentration hydroxide ion. At 30 °C, the constant (k) for the reaction is 1.0 × 10^-5 M^-1 s^-1

b. If the concentration of methyl chloride is decreased to 0.010 M, what will be the effect on

1. the rate of the reaction?

2. the rate constant for the reaction?

The rate constant for a reaction can be increased by ______ the stability of the reactant or by ______ the stability of the transition state.

From the Arrhenius equation, predict how

a. increasing the experimental activation energy affects the rate constant for a reaction.

From the Arrhenius equation, predict how

b. increasing the temperature affects the rate constant for a reaction.

a. Which reaction has a greater equilibrium constant: one with a rate constant of 1 × 10^-3 sec^-1 for the forward reaction and a rate constant of 1 × 10^-5 sec-1 for the reverse reaction, or one with a rate constant of 1 × 10^-2 sec^-1 for the forward reaction and a rate constant of 1 × 10^-3 sec^-1 for the reverse reaction?

b. If both reactions start with a reactant concentration of 1.0 M, which reaction will form the most product when the reactions have reached equilibrium?

Draw a reaction coordinate diagram for a two-step reaction in which the first step is endergonic, the second step is exergonic, and the overall reaction is endergonic. Label the reactants, products, intermediates, and transition states.

a. Which step in the reaction coordinate diagram shown here has the greatest free energy of activation in the forward direction?

b. Is the first-formed intermediate more apt to revert to reactants or go on to form products?

c. Which step is the rate-determining step of the reaction?

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Draw a reaction coordinate diagram for the following reaction in which C is the most stable and B the least stable of the three species and the transition state going from A to B is more stable than the transition state going from B to C:

a. How many intermediates are there?

b. How many transition states are there?

c. Which step has the greater rate constant in the forward direction?

d. Which step has the greater rate constant in the reverse direction?

Which of the following parameters would be different for a reaction carried out in the presence of a catalyst compared with the same reaction carried out in the absence of a catalyst?

∆G°, ∆H^‡, E_a, ∆S^‡, ∆H°, K_eq, ∆G^‡, ∆S°, k

What is each compound's systematic name?

a.

What is each compound's systematic name?

b.

What is each compound's systematic name?

c.

What is each compound's systematic name?

d.

e.

f.

Draw the structure of a hydrocarbon that has six carbon atoms and

a. three vinylic hydrogens and two allylic hydrogens.

b. three vinylic hydrogens and one allylic hydrogen.

c. three vinylic hydrogens and no allylic hydrogens.

Draw the condensed structure for each of the following:

a. (Z)-1,3,5-tribromo-2-pentene

b. (Z)-3-methyl-2-heptene

c. (E)-1,2-dibromo-3-isopropyl-2-hexene

Draw the condensed structure for each of the following:

d. vinyl bromide

e. 1,2-dimethylcyclopentene

f. diallylamine

Draw the skeletal structures for the compounds in Problem 42.

d. vinyl bromide

e. 1,2-dimethylcyclopentene

f. diallylamine

a. Draw the condensed structures and give the systematic names for all the alkenes with molecular formula C₆H₁₂, ignoring stereoisomers. (Hint: There are 13.)

b. Which of the alkenes have E and Z isomers?

c. Which of the alkenes is the most stable?

d. Which of the alkenes is the least stable?

Name the following:

a.

Name the following:

b.

Name the following:

c.

Name the following:

d.

e.

f.

Of the compounds you named in Problem 45:

a. Which is the most stable?

a.

b.

c.

d.

e.

f.

Of the compounds you named in Problem 45:

b. Which is the least stable?

a.

b.

c.

d.

e.

f.