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Ch.13 Alkenes, Alkynes, and Aromatic Compounds
McMurry - Fundamentals of General, Organic, and Biological Chemistry 8th Edition
McMurry8th EditionFundamentals of General, Organic, and Biological ChemistryISBN: 9780134015187당신이 사용하는 게 아니라요?교과서 변경
13장, 문제 7

Classify the following reactions as an addition, elimination, or substitution:
a. CH3Br + NaOH → CH3OH + NaBr
b. H2C═CH2 + HCl → CH3CH2Cl
c. CH3CH2Br → H2C═CH2 + HBr

검증된 단계별 안내
1
Step 1: Understand the three types of reactions: Addition reactions involve adding atoms or groups to a molecule, typically across a double or triple bond. Elimination reactions involve the removal of atoms or groups from a molecule, often resulting in the formation of a double or triple bond. Substitution reactions involve replacing one atom or group in a molecule with another.
Step 2: Analyze reaction (a): CH₃Br + NaOH → CH₃OH + NaBr. In this reaction, the bromine atom (Br) in CH₃Br is replaced by a hydroxyl group (OH) from NaOH, forming CH₃OH and NaBr. This is a substitution reaction.
Step 3: Analyze reaction (b): H₂C═CH₂ + HCl → CH₃CH₂Cl. Here, the double bond in ethene (H₂C═CH₂) is broken, and a hydrogen atom (H) and a chlorine atom (Cl) are added to the molecule, forming CH₃CH₂Cl. This is an addition reaction.
Step 4: Analyze reaction (c): CH₃CH₂Br → H₂C═CH₂ + HBr. In this reaction, a hydrogen atom (H) and a bromine atom (Br) are removed from CH₃CH₂Br, resulting in the formation of a double bond in H₂C═CH₂. This is an elimination reaction.
Step 5: Summarize the classifications: (a) is a substitution reaction, (b) is an addition reaction, and (c) is an elimination reaction. These classifications are based on the changes occurring in the reactants and products.

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주요 개념

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Addition Reactions

Addition reactions involve the combination of two or more reactants to form a single product. In these reactions, unsaturated compounds, such as alkenes or alkynes, react with other molecules, resulting in the formation of new bonds. A common example is the reaction of ethylene (H₂C═CH₂) with hydrogen chloride (HCl) to produce chloroethane (CH₃CH₂Cl).
추천 영상:
가이드 코스
2:55
Addition Reactions Concept 1

Elimination Reactions

Elimination reactions occur when a single reactant breaks down into two products, typically involving the removal of a small molecule like water or hydrogen halide. These reactions often convert saturated compounds into unsaturated ones. For instance, the reaction of bromoethane (CH₃CH₂Br) to form ethylene (H₂C═CH₂) and hydrogen bromide (HBr) is a classic example of an elimination reaction.
추천 영상:
가이드 코스
1:13
Alcohol Reactions Dehydration Reactions Example 1

Substitution Reactions

Substitution reactions involve the replacement of one atom or group in a molecule with another atom or group. This type of reaction is common in organic chemistry, particularly with alkyl halides. An example is the reaction of methyl bromide (CH₃Br) with sodium hydroxide (NaOH), where the bromine atom is replaced by a hydroxyl group, resulting in methanol (CH₃OH) and sodium bromide (NaBr).
추천 영상:
가이드 코스
5:07
Naming Alkanes with Substituents Example 1