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Ch.17 Carboxylic Acids and Their Derivatives
McMurry - Fundamentals of General, Organic, and Biological Chemistry 8th Edition
McMurry8th EditionFundamentals of General, Organic, and Biological ChemistryISBN: 9780134015187당신이 사용하는 게 아니라요?교과서 변경
모든 교과서McMurry 8th EditionCh.17 Carboxylic Acids and Their Derivatives문제 79
17장, 문제 79

Mention at least two simple chemical tests by which you can distinguish between benzaldehyde and benzoic acid.

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Step 1: Understand the chemical difference between benzaldehyde and benzoic acid. Benzaldehyde (C₆H₅CHO) is an aldehyde, while benzoic acid (C₆H₅COOH) is a carboxylic acid. This difference in functional groups will determine the chemical tests to distinguish them.
Step 2: Perform the Fehling's test. Aldehydes like benzaldehyde react with Fehling's solution to produce a red precipitate of copper(I) oxide (Cu₂O), while carboxylic acids like benzoic acid do not react. Add Fehling's solution to each compound and heat gently to observe the result.
Step 3: Conduct the sodium bicarbonate test. Carboxylic acids like benzoic acid react with sodium bicarbonate (NaHCO₃) to produce carbon dioxide gas (CO₂), which can be observed as effervescence. Aldehydes like benzaldehyde do not react with sodium bicarbonate. Add a small amount of NaHCO₃ to each compound and observe for bubbling.
Step 4: Optionally, perform the Tollens' test as an additional confirmation. Aldehydes like benzaldehyde react with Tollens' reagent to form a silver mirror on the test tube, while carboxylic acids like benzoic acid do not react. Add Tollens' reagent to each compound and observe the result.
Step 5: Record and compare the observations from the tests. Benzaldehyde will show a positive result in Fehling's and Tollens' tests but no reaction with sodium bicarbonate, while benzoic acid will show effervescence with sodium bicarbonate but no reaction in Fehling's or Tollens' tests.

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주요 개념

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Functional Groups

Benzaldehyde and benzoic acid are both aromatic compounds but differ in their functional groups. Benzaldehyde contains an aldehyde group (-CHO), while benzoic acid has a carboxylic acid group (-COOH). Understanding these functional groups is essential for predicting their chemical behavior and reactivity in tests.
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1:11
Functional Group Priorities Concept 1

Chemical Tests

Chemical tests are specific reactions used to identify the presence of certain functional groups in organic compounds. For instance, the Tollens' test can be used to distinguish benzaldehyde, which can be oxidized to a carboxylic acid, from benzoic acid, which does not react in the same way. Knowing these tests helps in differentiating between compounds based on their chemical properties.
추천 영상:
가이드 코스
14:42
Test for Anions

Solubility and pH

The solubility of benzaldehyde and benzoic acid in water varies due to their functional groups. Benzoic acid is more soluble in water because it can ionize to form benzoate ions, affecting the pH of the solution. This property can be exploited in tests, such as measuring pH changes, to distinguish between the two compounds.
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02:09
pH and pOH Calculations
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