Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions: (vi) 1. BH₃ 2. H₂O₂, NaOH
(k)

Verified step by step guidance

1. Step 1: Recognize the reaction type. The given reagents (1. BH₃, 2. H₂O₂, NaOH) indicate a hydroboration-oxidation reaction, which is used to convert an alkene into an alcohol.
2. Step 2: Understand the regioselectivity. Hydroboration-oxidation follows anti-Markovnikov addition, meaning the hydroxyl group (-OH) will attach to the less substituted carbon of the double bond.
3. Step 3: Understand the stereochemistry. The addition of BH₃ occurs in a syn fashion, meaning the boron and hydrogen add to the same side of the alkene. This stereochemistry is retained during the oxidation step, resulting in a syn addition of the hydroxyl group and hydrogen.
4. Step 4: Identify the structure of the starting alkene. Analyze the given alkene structure to determine which carbon atoms are part of the double bond and which is less substituted.
5. Step 5: Predict the product. Replace the double bond in the alkene with a single bond, and add a hydroxyl group (-OH) to the less substituted carbon and a hydrogen atom to the more substituted carbon, ensuring the syn stereochemistry is maintained.

Key Concepts

Hydroboration-Oxidation

Hydroboration-oxidation is a two-step reaction process used to convert alkenes into alcohols. In the first step, borane (BH₃) adds across the double bond of the alkene, resulting in a trialkylborane intermediate. The second step involves oxidation with hydrogen peroxide (H₂O₂) in the presence of a base (NaOH), which converts the boron atom into a hydroxyl group, yielding an alcohol.

Regioselectivity

Regioselectivity refers to the preference of a chemical reaction to yield one structural isomer over others when multiple products are possible. In hydroboration, the addition of BH₃ occurs in a syn fashion, leading to the formation of the more stable, less substituted alcohol due to the anti-Markovnikov rule, where the hydroxyl group ends up on the less substituted carbon.

Stereochemistry

Stereochemistry is the study of the spatial arrangement of atoms in molecules and how this affects their chemical behavior. In the hydroboration-oxidation reaction, the syn addition of BH₃ leads to specific stereochemical outcomes, which can influence the properties and reactivity of the resulting alcohol. Understanding stereochemistry is crucial for predicting the 3D orientation of the product.