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Ch. 2 The Chemical Basis of Life
Taylor - Campbell Biology: Concepts & Connections 10th Edition
Taylor, Simon, Dickey, Hogan10th EditionCampbell Biology: Concepts & ConnectionsISBN: 9780136538783Not the one you use?Change textbook
Chapter 2, Problem 4

What is chemically nonsensical about this structure?


Chemical structure showing a double bond between two carbon atoms and single bonds to hydrogen atoms.

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1
Examine the structure provided: The molecule consists of two carbon atoms connected by a double bond, each bonded to a single hydrogen atom.
Recall the valency of carbon: Carbon has a valency of 4, meaning it must form four bonds to satisfy its octet rule.
Analyze the bonds around each carbon atom: In the given structure, each carbon atom is forming only three bonds (two bonds in the double bond and one bond with hydrogen). This leaves the carbon atoms with an incomplete octet, which is chemically nonsensical.
Consider the implications of an incomplete octet: Atoms with incomplete octets are highly unstable and do not exist in this form under normal conditions.
Conclude that the structure violates basic chemical bonding rules: To make the structure chemically sensible, additional bonds or atoms would need to be added to satisfy the valency of carbon.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Valency of Carbon

Carbon has a valency of four, meaning it can form four covalent bonds with other atoms. In the given structure, each carbon atom is bonded to two hydrogen atoms and has a double bond with another carbon atom. This arrangement must satisfy the tetravalent nature of carbon, which is crucial for the stability of organic compounds.
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Double Bonds

A double bond consists of two pairs of shared electrons between two atoms, typically represented as a '=' in chemical structures. In the context of carbon, a double bond can occur between two carbon atoms, but each carbon must still fulfill its tetravalent requirement. If the structure does not allow for this, it can lead to an unstable or chemically nonsensical configuration.
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Hydrocarbon Structure

Hydrocarbons are organic compounds consisting solely of hydrogen and carbon. The structure shown in the image suggests a simple alkene, but if the carbon atoms do not have the correct number of hydrogen atoms to satisfy their valency, the structure becomes chemically nonsensical. Understanding the proper arrangement of hydrogen atoms in relation to carbon is essential for determining the validity of a hydrocarbon structure.
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