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Ch.16 Amines
McMurry - Fundamentals of GOB 8th Edition
McMurry8th EditionFundamentals of GOBISBN: 9780134015187Not the one you use?Change textbook
Chapter 16, Problem 11

Which of the following compounds are heterocyclic nitrogen compounds?
a.
b.
c.
d.

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1
Identify the definition of a heterocyclic nitrogen compound: A heterocyclic compound contains a ring structure with at least one atom in the ring being a nitrogen atom, and the rest of the atoms in the ring can be carbon or other elements.
Examine the structure of each compound provided in the images. Look for a ring structure and determine if nitrogen is one of the atoms in the ring.
For each compound, confirm whether the nitrogen atom is part of the ring (not just attached to the ring as a substituent). This is a key criterion for being a heterocyclic nitrogen compound.
Check if the ring structure is closed and stable, as heterocyclic compounds must have a complete ring system.
Classify each compound based on the above criteria and determine which ones meet the definition of heterocyclic nitrogen compounds.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Heterocyclic Compounds

Heterocyclic compounds are cyclic structures that contain at least one atom in the ring that is not carbon, typically nitrogen, oxygen, or sulfur. These compounds are significant in various fields, including pharmaceuticals and biochemistry, due to their diverse chemical properties and biological activities.
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Nitrogen in Heterocycles

Nitrogen is a common heteroatom in heterocyclic compounds, influencing their reactivity and stability. The presence of nitrogen can affect the electronic properties of the compound, making them essential in the design of drugs and agrochemicals, as they often participate in hydrogen bonding and coordination with metal ions.
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Identification of Heterocycles

Identifying heterocyclic nitrogen compounds involves recognizing the structural features that define them, such as the presence of a nitrogen atom within a ring. Familiarity with common heterocycles, like pyridine and imidazole, can aid in distinguishing these compounds from non-heterocyclic ones in chemical structures.
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