Draw a disaccharide of two cyclic mannose molecules attached by an α-1,4 glycosidic linkage. Explain why the glycosidic products in Problem 20.58 are not reducing sugars, but the product in this problem is a reducing sugar.
Ch.20 Carbohydrates
Chapter 20, Problem 63
How are amylose and amylopectin similar to each other, and how are they different from each other?
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Amylose and amylopectin are both polysaccharides composed of glucose monomers, making them similar in their basic building blocks and their role as energy storage molecules in plants.
Both amylose and amylopectin are components of starch, with amylose being the linear (unbranched) polymer and amylopectin being the branched polymer.
Amylose consists of glucose units linked by α(1→4) glycosidic bonds, forming a helical structure, while amylopectin contains both α(1→4) glycosidic bonds for the linear chains and α(1→6) glycosidic bonds at the branch points.
Amylopectin is more highly branched than amylose, which makes it more soluble in water and allows for quicker enzymatic breakdown during digestion compared to amylose.
The structural differences between amylose and amylopectin influence their physical properties, such as their ability to form gels and their digestibility, with amylose forming firmer gels and being digested more slowly.

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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Amylose
Amylose is a linear polymer made up of glucose units linked by α(1→4) glycosidic bonds. It typically forms a helical structure and is less soluble in water compared to amylopectin. Amylose constitutes about 20-30% of starch and is important for energy storage in plants.
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Amylopectin
Amylopectin is a branched polymer of glucose, consisting of α(1→4) glycosidic bonds along with α(1→6) bonds at the branching points. It is more soluble in water than amylose and makes up about 70-80% of starch. The branched structure allows for quicker enzymatic breakdown, providing rapid energy release.
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Starch Structure and Function
Starch is a polysaccharide composed of amylose and amylopectin, serving as a primary energy storage molecule in plants. The ratio of amylose to amylopectin affects the physical properties of starch, such as its digestibility and gelatinization. Understanding these differences is crucial for applications in food science and nutrition.
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Lactose and maltose are reducing disaccharides, but sucrose is a nonreducing disaccharide. Explain.
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Amylose (a form of starch) and cellulose are both polymers of glucose. What is the main structural difference between them? What roles do these two polymers have in nature?
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Trehalose, a disaccharide found in the blood of insects, has the following structure. What simple sugars would you obtain on hydrolysis of trehalose? (Hint: Rotate one of the rings in your head or redraw it rotated.)
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Are the α and β forms of the disaccharide lactose enantiomers of each other? Why or why not?
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D-Fructose can form a six-membered cyclic hemiacetal as well as the more prevalent five-membered cyclic form. Draw the α isomer of D-fructose in the six-membered ring.
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