문제 22.53d
Complete and balance the equation for each of the following reactions.
d.
문제 22.40d
Which compound in each of the following pairs is more ionic?
(d) BCl3 or AlCl3
문제 22.26e
Look at the location of elements A, B, C, and D in the following periodic table:
(e) Which of these oxides has the highest melting point? Which has the lowest melting point?
문제 22.44e
Consider the elements C, Se, B, Sn, and Cl. Identify which of these elements:
e. Forms a hydride with the empirical formula
문제 22.19f
Locate each of the following elements on the periodic table.
(f) Group 5A element that forms the strongest p bonds
문제 23
The following pictures represent structures of the hydrides of four second-row elements:
(1)
(2)
(3)
(4)
(c) Which compounds yield H2 gas when they are mixed together?
문제 24
In the following pictures of oxides, red spheres represent O atoms or ions, and green spheres represent atoms or ions of a second- or third-row element in its highest oxidation state.
(1)
(2)
(3)
(b) Identify each oxide as ionic or covalent.
문제 26
Look at the location of elements A, B, C, and D in the following periodic table:
(a) Write the formula of the oxide that has each of these elements in its highest oxidation state.
문제 30
The following models represent the structures of binary
oxides of second- and third-row elements in their highest
oxidation states:
(a) Identify the non-oxygen atom in each case, and write the molecular formula for each oxide.
- Which element in each of the following pairs has the higher ionization energy? (a) As or Cl (b) Mg or Ba
문제 32
- Arrange the following elements in order of increasing ionization energy: (a) N (b) Ca (c) Rb (d) Se.
문제 33
- Which element in each of the following pairs has the larger atomic radius? (a) Sn or P (b) Ge or Br
문제 34
- Arrange the following elements in order of increasing atomic radius: (a) Rb (b) F (c) Sb (d) S.
문제 35
- Which element in each of the following pairs has the higher electronegativity? (a) Sb or I (b) P or Sb
문제 36
- Arrange the following elements in order of increasing electronegativity: (a) Sr (b) Cl (c) Sn (d) Ge.
문제 37
- Which element in each of the following pairs has more metallic character? (a) Bi or As
문제 38
- Which element in each of the following pairs has more nonmetallic character? (b) Br or As
문제 39
- Which compound in each of the following pairs is more covalent? (a) CaO or NO (b) NH3 or KH (c) SnO2 or SiO2
문제 41
- Which of the following compounds are molecular, and which have an extended three-dimensional structure? (a) B2H6 (b) KAlSi3O8 (c) SO3 (d) GeCl4
문제 42
- Consider the elements C, Se, B, Sn, and Cl. Identify which of these elements: (a) Has a maximum oxidation state of +6, (b) Has the largest atomic radius, (c) Is the most electronegative.
문제 44
- Consider the elements N, Si, Al, S, and F. Identify which of these elements: (a) Has the highest ionization energy; (b) Has the most metallic character; (d) Forms a 2- anion.
문제 45
- At ordinary temperatures, sulfur exists as S8 but oxygen exists as O2. Explain.
문제 48
- Carbon, nitrogen, and oxygen form π bonds, but fluorine does not. Explain.
문제 49
문제 51
Consider the elements Mn, Al, C, S, and Si. Which element forms the strongest π bonds?
- Write a balanced equation for the synthesis of hydrogen using each of the following starting materials: (b) C, (c) CH4, (d) H2O.
문제 52
문제 53a,c
Complete and balance the equation for each of the following reactions.
a. Fe(s) + H+(aq) →
c. Al(s)+ H+(aq) →
- Calcium hydride is a convenient, portable source of hydrogen that is used, among other things, to inflate weather balloons. If the reaction of CaH2 with water is used to inflate a balloon with 2.0 * 10^5 L of H2 gas at 25 °C and 1.00 atm pressure, how many kilograms of CaH2 are needed?
문제 54
- The hydrogen-filled dirigible Hindenburg had a volume of 1.99 * 108 L. If the hydrogen used was produced by the reaction of carbon with steam, how many kilograms of carbon would have been needed to produce enough hydrogen to fill the dirigible at 20 °C and 740 mm pressure?
문제 55
- Write the chemical formula of a compound that contains hydrogen and each of the following elements. Which of these compounds are ionic, and which are covalent? (a) K (b) S
문제 57
- In the following compound, is hydrogen present as H+, H-, or a covalently bound H atom? (b) PH3
문제 58
Ch.22 - The Main Group Elements
