Skip to main content
Ch. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics
Mullins - Organic Chemistry: A Learner Centered Approach 1st Edition
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471당신이 사용하는 게 아니라요?교과서 변경
모든 교과서Mullins 1st EditionCh. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics문제 3b
4장, 문제 3b

Which is the most stable base in each pair?
(b) HS– and HO–

검증된 단계별 안내
1
Compare the conjugate acids of the given bases (HS⁻ and HO⁻). The stability of a base is inversely related to the strength of its conjugate acid. The weaker the conjugate acid, the more stable the base.
The conjugate acid of HS⁻ is H₂S, and the conjugate acid of HO⁻ is H₂O. Analyze the acid strengths of H₂S and H₂O by considering their positions in the periodic table and their bond strengths.
Sulfur (S) is larger and less electronegative than oxygen (O). This means the H–S bond in H₂S is weaker and more easily broken compared to the H–O bond in H₂O, making H₂S a stronger acid than H₂O.
Since H₂S is a stronger acid than H₂O, its conjugate base (HS⁻) is less stable compared to the conjugate base of H₂O (HO⁻).
Conclude that HO⁻ is the more stable base in this pair because it is derived from the weaker acid (H₂O).

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
2m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Acidity and Basicity

Acidity and basicity are fundamental concepts in organic chemistry that describe the tendency of a substance to donate or accept protons (H+ ions). A stronger acid has a weaker conjugate base, while a stronger base has a weaker conjugate acid. Understanding the relative strengths of acids and bases is crucial for predicting the stability of ions like HS– and HO–.
추천 영상:
06:21
Understanding the difference between basicity and nucleophilicity.

Conjugate Acid-Base Pairs

Conjugate acid-base pairs consist of two species that differ by the presence or absence of a proton. For example, HS– is the conjugate base of H2S, while HO– is the conjugate base of H2O. The stability of these pairs can be assessed by examining the strength of their corresponding acids, which influences the stability of the bases.
추천 영상:
가이드 코스
2:56
Base Pairing Concept 1

Electronegativity and Charge Stability

Electronegativity refers to the ability of an atom to attract electrons in a bond. In the context of anions like HS– and HO–, the stability of the negative charge is influenced by the electronegativity of the atom bearing the charge. A more electronegative atom can better stabilize a negative charge, affecting the overall stability of the base.
추천 영상:
1:47
Electronegativity
관련 실천
교과서 질문

Predict which side of the equilibrium is favored for each of the chair–chair interconversions (ring flips) shown.

(a)

1299
views
교과서 질문

Which is the most acidic compound in each pair?

(a)

1482
views
교과서 질문

Which is the most stable base in each pair?

(a)

1129
views
교과서 질문

Predict which side of the equilibrium is favored for each of the chair–chair interconversions (ring flips) shown.

(c)

1064
views
교과서 질문

Which is the most acidic compound in each pair?

(b) HF vs. HCl

1489
views
교과서 질문

Which is the most stable base in each pair?

(c) NH3 vs. H2O

1136
views