To this point, hydrogenation has always been an exothermic process. Using the numbers from Figure 21.6, calculate ∆H^o_hydr for each step of the reduction of benzene.
∆H₁ + ∆H₂ + ∆H₃ = ∆H_tot = ―49.5 kcal /mol (―208 kJ/mol)

검증된 단계별 안내

Step 1: Understand the problem. The hydrogenation of benzene occurs in three steps, each involving the addition of H₂ to reduce one double bond. The total enthalpy change (∆Htot) for the complete reduction of benzene to cyclohexane is given as -49.5 kcal/mol (-208 kJ/mol). We need to calculate the enthalpy change (∆H₁, ∆H₂, ∆H₃) for each step.

Step 2: Recognize that the total enthalpy change is the sum of the enthalpy changes for each step: ∆H₁ + ∆H₂ + ∆H₃ = ∆Htot. This equation will guide the calculation.

Step 3: Note that benzene has resonance stabilization energy, which makes the first hydrogenation step (∆H₁) less exothermic compared to the subsequent steps. This is because breaking the aromaticity of benzene requires additional energy.

Step 4: Use the data from Figure 21.6 (if available) to determine the individual enthalpy changes for ∆H₁, ∆H₂, and ∆H₃. If the values for ∆H₁ or any other step are provided in Section 23.2.1, use them to solve for the remaining enthalpy changes.

Step 5: Rearrange the equation ∆H₁ + ∆H₂ + ∆H₃ = ∆Htot to solve for the unknown values. For example, if ∆H₁ is known, subtract it from ∆Htot to find the sum of ∆H₂ and ∆H₃, and then use additional data to determine their individual values.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.

영상 길이:

도움이 되었나요?

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Hydrogenation

Hydrogenation is a chemical reaction that involves the addition of hydrogen (H₂) to an unsaturated compound, typically alkenes or alkynes, converting them into saturated hydrocarbons. In the context of benzene, hydrogenation reduces the aromatic ring to form cyclohexane. This process is generally exothermic, meaning it releases energy, which is crucial for calculating the enthalpy changes involved.

Enthalpy Change (ΔH)

Enthalpy change (ΔH) is a measure of the heat content of a system at constant pressure. It indicates whether a reaction is exothermic (releases heat, ΔH < 0) or endothermic (absorbs heat, ΔH > 0). In the hydrogenation of benzene, the total enthalpy change is the sum of the individual steps (ΔH₁, ΔH₂, ΔH₃), which must equal the overall change provided in the question.

Thermochemical Equations

Thermochemical equations represent the relationship between the heat absorbed or released during a chemical reaction and the stoichiometry of the reaction. They allow for the calculation of enthalpy changes for each step in a multi-step reaction, such as the hydrogenation of benzene. By knowing the total enthalpy change and the individual steps, one can solve for the unknown enthalpy changes (ΔH₁, ΔH₂, ΔH₃) in the reaction sequence.

To this point, hydrogenation has always been an exothermic process. Using the numbers from Fig­ure 21.6, calculate ∆Hohydr for each step of the reduction of benzene. ∆H1 + ∆H2 + ∆H3 = ∆Htot = ―49.5 kcal /mol (―208 kJ/mol)