문제 50a
Propose mechanisms for the following reactions.
(a)
문제 50b
Propose mechanisms for the following reactions.
(b)
문제 50c
Propose mechanisms for the following reactions.
(c)
문제 50d
Propose mechanisms for the following reactions.
(d)
문제 50e
Propose mechanisms for the following reactions.
(e)
문제 50f
Propose mechanisms for the following reactions.
(f)
문제 51a
Show how you would accomplish the following syntheses efficiently and in good yield. You may use any necessary reagents.
(a) acetaldehyde → lactic acid, CH3CH(OH)COOH
문제 51b
Show how you would accomplish the following syntheses efficiently and in good yield. You may use any necessary reagents.
(b)
문제 51d
Show how you would accomplish the following synthetic conversions efficiently and in good yield. You may use any necessary additional reagents and solvents.
(d)
문제 51e
Show how you would accomplish the following syntheses efficiently and in good yield. You may use any necessary reagents.
(e)
문제 51g
Show how you would accomplish the following syntheses efficiently and in good yield. You may use any necessary reagents.
(g)
문제 52a
Show how you would synthesize the following derivatives from appropriate carbonyl compounds.
(a)
문제 52b
Show how you would synthesize the following derivatives from appropriate carbonyl compounds.
(b)
문제 52c
Show how you would synthesize the following derivatives from appropriate carbonyl compounds.
(c)
문제 52d
Show how you would synthesize the following derivatives from appropriate carbonyl compounds.
(d)
문제 53a
Predict the products formed when cyclohexanone reacts with the following reagents.
(a) CH3NH2, H+
문제 53b
Predict the products formed when cyclohexanone reacts with the following reagents.
(b) excess CH3OH, H+
문제 53c
Predict the products formed when cyclohexanone reacts with the following reagents.
(c) hydroxylamine and weak acid
문제 53d
Predict the products formed when cyclohexanone reacts with the following reagents.
(d) ethylene glycol and p-toluenesulfonic acid
문제 53e
Predict the products formed when cyclohexanone reacts with the following reagents.
(e) phenylhydrazine and weak acid
문제 53f
Predict the products formed when cyclohexanone reacts with the following reagents.
(f) PhMgBr and then mild H3O+
문제 53g
Predict the products formed when cyclohexanone reacts with the following reagents.
g. Tollens reagent
문제 53h
Predict the products formed when cyclohexanone reacts with the following reagents.
(h) sodium acetylide, then mild H3O+
문제 53i
Predict the products formed when cyclohexanone reacts with the following reagents.
(i) hydrazine, then hot, fused KOH
문제 53k
Predict the products formed when cyclohexanone reacts with the following reagents.
(k) sodium cyanide
문제 53l
Predict the products formed when cyclohexanone reacts with the following reagents.
(l) acidic hydrolysis of the product from (k)
문제 54a
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(a) PhMgBr, then H3O+
문제 54b
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
b. Tollens reagent
문제 54c
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(c) semicarbazide and weak acid
문제 54d
Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagents.
(d) excess ethanol and acid
Ch. 18 - Ketones and Aldehydes
