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Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 130

One watt (W) is equal to 1 J/s. Assuming that 5.0% of the energy output of a 75 W light bulb is visible light and that the average wavelength of the light is 550 nm, how many photons are emitted by the light bulb each second?

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Convert the power of the light bulb to energy per second: 75 W = 75 J/s.
Calculate the energy output in visible light: 5.0% of 75 J/s.
Use the energy of a photon formula: \( E = \frac{hc}{\lambda} \), where \( h \) is Planck's constant, \( c \) is the speed of light, and \( \lambda \) is the wavelength (550 nm).
Convert the wavelength from nanometers to meters for use in the formula.
Divide the total energy output in visible light by the energy of a single photon to find the number of photons emitted per second.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Energy and Power

Power is the rate at which energy is transferred or converted, measured in watts (W), where 1 W equals 1 joule per second (J/s). In this context, the light bulb's power rating indicates how much energy it consumes per second, which is crucial for calculating the total energy output in visible light.
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Power and Root Functions Example

Photon Energy

The energy of a photon is determined by its wavelength, given by the equation E = hc/λ, where E is energy, h is Planck's constant, c is the speed of light, and λ is the wavelength. For light with a wavelength of 550 nm, this relationship allows us to calculate the energy of each emitted photon, which is essential for determining the total number of photons emitted.
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Calculating Photon Emission

To find the number of photons emitted per second, we first calculate the total energy output in visible light by multiplying the power of the bulb by the percentage of energy that is visible. Then, we divide this energy by the energy of a single photon to determine how many photons are emitted each second, linking energy output to photon count.
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Related Practice
Textbook Question

Imagine a universe in which the four quantum numbers can have the same possible values as in our universe except that the angular-momentum quantum number l can have integral values of 0, 1, 2...n + 1 (instead of 0, 1, 2..., n - 1). (c) Draw an orbital-filling diagram for the element with atomic number 12.

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Open Question
Draw orbital-filling diagrams for the following atoms. Show each electron as an up or down arrow, and use the abbreviation of the preceding noble gas to represent inner-shell electrons. (a) Sr (b) Cd (c) Atom with Z = 22 (d) Atom with Z = 34
Open Question
The atomic radii of Y (180 pm) and La (187 pm) are significantly different, but the radii of Zr (160 pm) and Hf (159 pm) are essentially identical. Explain.
Textbook Question
Microwave ovens work by irradiating food with microwave radiation, which is absorbed and converted into heat. Assum-ing that radiation with l = 15.0 cm is used, that all the energy is converted to heat, and that 4.184 J is needed to raise the temperature of 1.00 g of water by 1.00 °C, how many photons are necessary to raise the temperature of a 350 mL cup of water from 20 °C to 95 °C?
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Textbook Question
The amount of energy necessary to remove an electron from an atom is a quantity called the ionization energy, Ei. This energy can be measured by a technique called photoelectron spectroscopy, in which light of wavelength l is directed at an atom, causing an electron to be ejected. The kinetic energy of the ejected electron (Ek) is measured by determining its veloc-ity, v (Ek = mv2/2), and Ei is then calculated using the conservation of energy principle. That is, the energy of the incident light equals Ei plus Ek. What is the ionization energy of selenium atoms in kilojoules per mole if light with l = 48.2 nm produces electrons with a velocity of 2.371 * 106 m/s? The mass, m, of an electron is 9.109 * 10-31 kg.
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Textbook Question
X rays with a wavelength of 1.54 * 10-10 m are produced when a copper metal target is bombarded with high-energy electrons that have been accelerated by a voltage difference of 30,000 V. The kinetic energy of the electrons equals the product of the voltage difference and the electronic charge in coulombs, where 1 volt-coulomb = 1 J. (a) What is the kinetic energy in joules and the de Broglie wavelength in meters of an electron that has been accel-erated by a voltage difference of 30,000 V?
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