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Ch.9 Solutions
McMurry - Fundamentals of GOB 8th Edition
McMurry8th EditionFundamentals of GOBISBN: 9780134015187Not the one you use?Change textbook
Chapter 9, Problem 93a

Cobalt(II) chloride, a blue solid, can absorb water from the air to form cobalt(II) chloride hexahydrate, a pink solid. The equilibrium is so sensitive to moisture in the air that CoCl2 is used as a humidity indicator.
a. Write a balanced equation for the equilibrium. Be sure to include water as a reactant to produce the hexahydrate.

Verified step by step guidance
1
Identify the chemical formula for cobalt(II) chloride, which is CoCl₂, and the formula for its hexahydrate, which is CoCl₂·6H₂O.
Recognize that the reaction involves the absorption of water (H₂O) from the air to form the hexahydrate. This means water is a reactant in the equation.
Write the unbalanced equation: CoCl₂ (s) + H₂O (g) ⇌ CoCl₂·6H₂O (s).
Balance the equation by ensuring the number of water molecules matches the hexahydrate formula. Since the hexahydrate contains 6 water molecules, the balanced equation becomes: CoCl₂ (s) + 6H₂O (g) ⇌ CoCl₂·6H₂O (s).
Verify that the equation is balanced by checking that the number of each type of atom (Co, Cl, H, O) is the same on both sides of the equation.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Chemical Equilibrium

Chemical equilibrium occurs when the rates of the forward and reverse reactions are equal, resulting in constant concentrations of reactants and products. In the case of cobalt(II) chloride, the equilibrium between the anhydrous form and the hydrated form is influenced by external factors like humidity, demonstrating how environmental conditions can shift the balance of a chemical reaction.
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Hydration Reaction

A hydration reaction involves the addition of water to a substance, leading to the formation of a hydrate. For cobalt(II) chloride, the reaction with water results in the formation of cobalt(II) chloride hexahydrate, which is a solid that contains water molecules integrated into its crystal structure, changing its color from blue to pink.
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Balanced Chemical Equation

A balanced chemical equation represents a chemical reaction with equal numbers of each type of atom on both sides of the equation. For the hydration of cobalt(II) chloride, the balanced equation must reflect the conversion of CoCl₂ and water into CoCl₂·6H₂O, ensuring that the number of cobalt, chlorine, and hydrogen atoms is conserved throughout the reaction.
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Related Practice
Textbook Question

Uric acid, the principal constituent of some kidney stones, has the formula C5H4N4O3. In aqueous solution, the solubility of uric acid is only 0.067 g/L. Express this concentration in (m/v)%, in parts per million, and in molarity.

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Textbook Question

Emergency treatment of cardiac arrest victims sometimes involves injection of a calcium chloride solution directly into the heart muscle. How many grams of CaCl2 are administered in an injection of 5.0 mL of a 5.0% (m/v) solution? How many milliequivalents of Ca2+?

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Textbook Question

Ammonia, NH3, is very soluble in water (51.8 g/L at 20 °C and 760 mmHg).

a. Show how NH3 can hydrogen bond to water.

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Textbook Question

How many milliliters of 0.150 M BaCl2 are needed to react completely with 35.0 mL of 0.200 M Na2SO4? How many grams of BaSO4 will be formed?

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Textbook Question

Many compounds are only partially dissociated into ions in aqueous solution. Trichloroacetic acid (CCl3CO2H), for instance, is partially dissociated in water according to the equation

CCl3CO2H(aq) → H+(aq) + CCl3CO2⁻ aq)

For a solution prepared by dissolving 1.00 mol of trichloroacetic acid in 1.00 kg of water, 36.0% of the trichloroacetic acid dissociates to form H+ and CCl3CO2⁻ ions.

a. What is the total concentration of dissolved ions and molecules in 1 kg of water?

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Textbook Question

Many compounds are only partially dissociated into ions in aqueous solution. Trichloroacetic acid (CCl3CO2H), for instance, is partially dissociated in water according to the equation

CCl3CO2H(aq) → H+(aq) + CCl3CO2⁻ aq)

For a solution prepared by dissolving 1.00 mol of trichloroacetic acid in 1.00 kg of water, 36.0% of the trichloroacetic acid dissociates to form H+ and CCl3CO2⁻ ions.

b. What is the freezing point of this solution? (The freezing point of 1 kg of water is lowered 1.86 °C for each mole of solute particles.)

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