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Ch.14 Some Compounds with Oxygen, Sulfur, or a Halogen
McMurry - Fundamentals of GOB 8th Edition
McMurry8th EditionFundamentals of GOBISBN: 9780134015187Not the one you use?Change textbook
Chapter 14, Problem 34f

Draw structures corresponding to the following names:
f. 3,3-Dimethyl-1,6-heptanediol

Verified step by step guidance
1
Step 1: Start by identifying the parent chain. The name '3,3-Dimethyl-1,6-heptanediol' indicates that the parent chain is 'heptane,' which consists of 7 carbon atoms in a straight chain.
Step 2: Add the functional groups. The suffix '-diol' indicates the presence of two hydroxyl (-OH) groups. The numbers '1' and '6' specify that these hydroxyl groups are attached to the first and sixth carbons of the heptane chain.
Step 3: Add the substituents. The prefix '3,3-Dimethyl' indicates that there are two methyl (-CH₃) groups attached to the third carbon of the heptane chain.
Step 4: Assemble the structure. Draw a straight chain of 7 carbon atoms (heptane). Attach hydroxyl groups (-OH) to the first and sixth carbons. Then, attach two methyl groups (-CH₃) to the third carbon.
Step 5: Verify the structure. Ensure that all carbons have four bonds, the hydroxyl groups are correctly placed on carbons 1 and 6, and the two methyl groups are correctly attached to carbon 3. Confirm that the structure matches the IUPAC name.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

IUPAC Nomenclature

IUPAC nomenclature is a systematic method for naming chemical compounds. It provides a set of rules to derive the names of organic molecules based on their structure, including the identification of functional groups, the longest carbon chain, and the position of substituents. Understanding these rules is essential for accurately interpreting and drawing chemical structures.
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Structural Isomers

Structural isomers are compounds that have the same molecular formula but differ in the arrangement of atoms. In the case of 3,3-Dimethyl-1,6-heptanediol, recognizing how the carbon skeleton can be arranged differently while maintaining the same formula is crucial for drawing the correct structure. This concept highlights the diversity of organic compounds and the importance of structural representation.
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Functional Groups

Functional groups are specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. In 3,3-Dimethyl-1,6-heptanediol, the presence of hydroxyl (-OH) groups indicates that it is a diol, which influences its reactivity and properties. Identifying functional groups is key to understanding the behavior and classification of organic compounds.
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