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Ch.6 - Ionic Compounds: Periodic Trends and Bonding Theory
Chapter 6, Problem 42

What is the electron configuration of Ti2+?

Verified step by step guidance
1
Step 1: Identify the atomic number of titanium (Ti), which is 22. This means a neutral titanium atom has 22 electrons.
Step 2: Write the electron configuration for a neutral titanium atom. The configuration is: \(1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 3d^2\).
Step 3: Recognize that \(Ti^{2+}\) means the titanium atom has lost 2 electrons.
Step 4: Remove electrons starting from the outermost shell. Electrons are removed from the 4s orbital first, followed by the 3d orbital if necessary.
Step 5: Adjust the electron configuration by removing 2 electrons from the 4s orbital: \(1s^2 2s^2 2p^6 3s^2 3p^6 3d^2\).

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

Electron configuration describes the distribution of electrons in an atom's orbitals. It follows the Aufbau principle, which states that electrons fill the lowest energy orbitals first, and is typically represented using a notation that indicates the number of electrons in each subshell (s, p, d, f). Understanding this concept is crucial for determining the electron arrangement in ions and neutral atoms.
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Ionization and Charge

Ionization refers to the process of adding or removing electrons from an atom, resulting in the formation of ions. The charge of an ion indicates the difference between the number of protons and electrons. For Ti2+, the '2+' signifies that two electrons have been removed from the neutral titanium atom, which has an atomic number of 22, leading to a total of 20 electrons in the ion.
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Transition Metals and d-Orbitals

Transition metals, such as titanium, have partially filled d-orbitals, which play a significant role in their chemical properties and electron configurations. The electron configuration of transition metals can be complex due to the involvement of d-orbitals, especially when forming ions. For Ti2+, the removal of electrons typically occurs from the 4s orbital before the 3d orbital, which is essential for accurately determining its electron configuration.
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