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Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 76

Draw the Lewis structure for NO+ . Is the nitrogen– oxygen bond in NO+ longer, shorter, or the same length as the nitrogen–oxygen bond in NO? Explain. Draw the Lewis structure for NO+ .

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Lewis Structures

Lewis structures are diagrams that represent the bonding between atoms in a molecule and the lone pairs of electrons that may exist. They use dots to represent valence electrons and lines to represent bonds between atoms. Understanding how to draw Lewis structures is essential for predicting molecular geometry, bond lengths, and the overall reactivity of the molecule.
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Lewis Dot Structures: Ions

Bond Length

Bond length is the distance between the nuclei of two bonded atoms. It is influenced by the type of bond (single, double, or triple) and the atoms involved. Generally, as the number of shared electron pairs increases, the bond length decreases, leading to shorter and stronger bonds. This concept is crucial for comparing bond lengths in different molecules.
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Formal Charge

Formal charge is a theoretical charge assigned to an atom in a molecule, calculated based on the number of valence electrons, the number of non-bonding electrons, and the number of bonds. It helps in determining the most stable Lewis structure by minimizing formal charges across the molecule. In the case of NO+ and NO, analyzing formal charges can provide insight into the stability and bond characteristics of the nitrogen-oxygen bond.
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Related Practice
Textbook Question

There are many Lewis structures you could draw for sulfuric acid, H2SO4 (each H is bonded to an O). (b) What Lewis structure(s) would you draw to minimize formal charge?

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Textbook Question

Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, H2PO4-, in which the H atoms are bonded to O atoms. (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?

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Textbook Question

State whether each of these statements is true or false. (e) The longer the bond, the more energy is stored chemical bonds.

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Textbook Question

Consider the lattice energies of the following Group 2A compounds: BeH2, 3205 kJ/mol; MgH2, 2791 kJ/mol; CaH2, 2410 kJ/mol; SrH2, 2250 kJ/mol; BaH2, 2121 kJ/mol. (a) What is the oxidation number of H in these compounds?

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Textbook Question

The ionic compound CaO crystallizes with the same structure as sodium chloride (Figure 8.3). (a) In this structure, how many O2- are in contact with each Ca2+ ion (Hint: Remember the pattern of ions shown in Figure 8.3 repeats over and over again in all three directions.)

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Textbook Question

Construct a Born–Haber cycle for the formation of the hypothetical compound NaCl2, where the sodium ion has a 2+ charge (the second ionization energy for sodium is given in Table 7.2). (a) How large would the lattice energy need to be for the formation of NaCl2 to be exothermic?

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