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Ch.10 - Gases: Their Properties & Behavior
Chapter 10, Problem 48d

Assume that you have a cylinder with a movable piston. What would happen to the gas pressure inside the cylinder if you were to do the following? (d) Halve the Kelvin temperature and triple the volume

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Step 1: Understand the relationship between pressure, volume, and temperature in a gas. This relationship is described by the ideal gas law, which is PV = nRT, where P is the pressure, V is the volume, n is the number of moles of gas, R is the ideal gas constant, and T is the temperature in Kelvin.
Step 2: In this problem, we are changing the volume and the temperature, but the number of moles of gas and the ideal gas constant remain the same. Therefore, we can write the relationship as P1V1/T1 = P2V2/T2, where the subscripts 1 and 2 refer to the initial and final states, respectively.
Step 3: We are told that the final volume is three times the initial volume (V2 = 3V1) and the final temperature is half the initial temperature (T2 = 0.5T1). Substitute these values into the equation from step 2.
Step 4: After substitution, the equation becomes P1V1/T1 = P2*(3V1)/(0.5T1). Simplify this equation to find the relationship between the initial and final pressures.
Step 5: From the simplified equation, you can see that the final pressure is related to the initial pressure, volume, and temperature changes. Solve for P2 to find the final pressure of the gas in the cylinder.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure, volume, temperature, and number of moles of a gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is the absolute temperature in Kelvin. Understanding this relationship is crucial for predicting how changes in one variable affect the others.
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Gas Pressure

Gas pressure is defined as the force exerted by gas molecules colliding with the walls of their container. It is influenced by the number of gas particles, their temperature, and the volume of the container. When the volume increases or the temperature decreases, the pressure typically decreases, as fewer collisions occur against the walls.
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Temperature in Kelvin

Temperature in Kelvin is the absolute temperature scale used in scientific calculations, where 0 K represents absolute zero, the point at which molecular motion ceases. In gas laws, temperature must be expressed in Kelvin to ensure direct proportionality with pressure and volume. Halving the Kelvin temperature significantly impacts gas behavior, as it indicates a decrease in kinetic energy of the gas molecules.
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