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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 135b

A compound with the formula XOCl2 reacts with water, yielding HCl and another acid H2XO3, which has two acidic hydrogens that react with NaOH. When 0.350 g of XOCl2 was added to 50.0 mL of water and the resultant solution was titrated, 96.1 mL of 0.1225 M NaOH was required to react with all the acid. (b) What are the atomic mass and identity of element X?

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Determine the moles of NaOH used in the titration. Use the molarity and volume of the NaOH solution. The formula to calculate moles is: \( \text{Moles} = \text{Molarity} \times \text{Volume in liters} \).
Since H2XO3 has two acidic hydrogens, each mole of H2XO3 will react with two moles of NaOH. Use this stoichiometric relationship to calculate the moles of H2XO3 produced in the reaction.
Knowing the moles of H2XO3 and the fact that each mole of XOCl2 produces one mole of H2XO3, determine the moles of XOCl2 that reacted.
Calculate the molar mass of XOCl2 using the mass of XOCl2 given and the moles of XOCl2 calculated. The formula for molar mass is: \( \text{Molar Mass} = \frac{\text{Mass}}{\text{Moles}} \).
Determine the atomic mass of X by subtracting the masses of the oxygen and chlorine atoms from the molar mass of XOCl2. Use the known atomic masses of oxygen (16.00 g/mol) and chlorine (35.45 g/mol) for this calculation.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions. It involves using balanced chemical equations to determine the relationships between the amounts of substances consumed and produced. In this question, stoichiometry is essential for understanding how the amounts of XOCl2, HCl, and H2XO3 relate to the volume and concentration of NaOH used in the titration.
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Titration

Titration is a laboratory technique used to determine the concentration of a solute in a solution. It involves the gradual addition of a titrant (in this case, NaOH) to a solution until a reaction reaches completion, indicated by a color change or a specific endpoint. Understanding titration is crucial for calculating the moles of acid present in the solution, which will help identify the compound XOCl2 and the element X.
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Acid-Base Reactions

Acid-base reactions involve the transfer of protons (H+) between reactants, resulting in the formation of water and a salt. In this scenario, HCl and H2XO3 are the acids produced from the reaction of XOCl2 with water. Recognizing the nature of these acids and their reactions with NaOH is vital for determining the total acidity of the solution and ultimately identifying the element X based on the stoichiometric relationships.
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Related Practice
Textbook Question
Calcium levels in blood can be determined by adding oxa-late ion to precipitate calcium oxalate, CaC2O4, followed by dissolving the precipitate in aqueous acid and titrating the resulting oxalic acid (H2C2O4) with KMnO4: How many milligrams of Ca2+ are present in 10.0 mL of blood if 21.08 mL of 0.000 988 M KMnO4 solution is needed for the titration?
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Textbook Question
Assume that you have 1.00 g of a mixture of benzoic acid (Mol. wt. = 122) and gallic acid (Mol. wt. = 170)), both of which contain one acidic hydrogen that reacts with NaOH. On titrating the mixture with 0.500 M NaOH, 14.7 mL of base is needed to completely react with both acids. What mass in grams of each acid is present in the original mixture?
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Textbook Question

A compound with the formula XOCl2 reacts with water, yielding HCl and another acid H2XO3, which has two acidic hydrogens that react with NaOH. When 0.350 g of XOCl2 was added to 50.0 mL of water and the resultant solution was titrated, 96.1 mL of 0.1225 M NaOH was required to react with all the acid. (a) Write a balanced equation for the reaction of XOCl2 with H2O.

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Textbook Question
A procedure for determining the amount of iron in a sample is to convert the iron to Fe2+ and then titrate it with a solu-tion of Ce(NH4)2(NO3)6: What is the mass percent of iron in a sample if 1.2284 g of the sample requires 54.91 mL of 0.1018 M Ce(NH4)2(NO3)6 for complete reaction?
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Textbook Question

Some metals occur naturally in their elemental state while others occur as compounds in ores. Gold, for instance, is found as the free metal; mercury is obtained by heating mercury(II) sulfide ore in oxygen; and zinc is obtained by heating zinc(II) oxide ore with coke (carbon). Judging from their positions in the activity series, which of the metals sil-ver, platinum, and chromium would probably be obtained by (a) finding it in its elemental state?

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Textbook Question

Some metals occur naturally in their elemental state while others occur as compounds in ores. Gold, for instance, is found as the free metal; mercury is obtained by heating mercury(II) sulfide ore in oxygen; and zinc is obtained by heating zinc(II) oxide ore with coke (carbon). Judging from their positions in the activity series, which of the metals sil-ver, platinum, and chromium would probably be obtained by (c) heating its oxide with coke?

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