Chapter 8, Problem 67a
There are many Lewis structures you could draw for sulfuric acid, H2SO4 (each H is bonded to an O). (a) What Lewis structure(s) would you draw to satisfy the octet rule?
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In the vapor phase, BeCl2 exists as a discrete molecule. (a) Draw the Lewis structure of this molecule, using only single bonds. Does this Lewis structure satisfy the octet rule?
In the vapor phase, BeCl2 exists as a discrete molecule. (c) On the basis of the formal charges, which Lewis structure is expected to be dominant for BeCl2?
(a) Describe the molecule xenon trioxide, XeO3, using four possible Lewis structures, one each with zero, one, two, or three Xe¬O double bonds. (b) Do any of these resonance structures satisfy the octet rule for every atom in the molecule? (c) Do any of the four Lewis structures have multiple resonance structures? If so, how many resonance structures do you find? (d) Which of the Lewis structures in part (a) yields the most favorable formal charges for the molecule?
There are many Lewis structures you could draw for sulfuric acid, H2SO4 (each H is bonded to an O). (b) What Lewis structure(s) would you draw to minimize formal charge?
Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, H2PO4-, in which the H atoms are bonded to O atoms. (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?
State whether each of these statements is true or false. (e) The longer the bond, the more energy is stored chemical bonds.