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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 2

Molecules in the upper atmosphere tend to contain double and triple bonds rather than single bonds. Suggest an explanation. [Section 18.1]

Verified step by step guidance
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Step 1: Understand the context of the problem by recognizing that the upper atmosphere is exposed to high-energy radiation, such as ultraviolet (UV) light from the sun.
Step 2: Recall that double and triple bonds are generally stronger than single bonds. This means they require more energy to break.
Step 3: Consider that molecules with stronger bonds (double and triple bonds) are more stable in environments with high-energy radiation because they are less likely to be broken apart by the radiation.
Step 4: Recognize that the presence of double and triple bonds in molecules helps them resist decomposition in the harsh conditions of the upper atmosphere.
Step 5: Conclude that the stability provided by double and triple bonds makes these molecules more prevalent in the upper atmosphere, where they can withstand the intense energy from solar radiation.

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Bond Strength and Stability

Double and triple bonds are stronger than single bonds due to the increased number of shared electron pairs between atoms. This greater bond strength contributes to the stability of molecules in the harsh conditions of the upper atmosphere, where high energy from solar radiation can break weaker single bonds.
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Reactivity of Atmospheric Molecules

Molecules in the upper atmosphere are often exposed to intense ultraviolet (UV) radiation, which can lead to the formation of reactive species. The presence of double and triple bonds allows these molecules to participate in various photochemical reactions, making them more adaptable to the dynamic atmospheric environment.
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Molecular Geometry and Polarity

The geometry of molecules with double and triple bonds can influence their polarity and interactions with other atmospheric components. The linear or planar structures resulting from these bonds can enhance the ability of these molecules to absorb UV light, further stabilizing them in the upper atmosphere.
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Related Practice
Textbook Question

At 273 K and 1 atm pressure, 1 mol of an ideal gas occupies 22.4 L. (Section 10.4) (b) Looking at Figure 18.1, we see that the temperature is lower at 85 km altitude than at 50 km. Does this mean that one mole of an ideal gas would occupy less volume at 85 km than at 50 km? Explain.

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Textbook Question

At 273 K and 1 atm pressure, 1 mol of an ideal gas occupies 22.4 L. (Section 10.4) (c) In which parts of the atmosphere would you expect gases to behave most ideally (ignoring any photochemical reactions)? [Section 18.1]

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Textbook Question

The figure shows the three lowest regions of Earth's atmo- sphere.

(d) An aurora borealis is due to excitation of atoms and molecules in the atmosphere 55–95 km above Earth's surface. Which regions in the figure are involved in an aurora borealis?

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Textbook Question

You are working with an artist who has been commissioned to make a sculpture for a big city in the eastern United States. The artist is wondering what material to use to make her sculpture because she has heard that acid rain in the eastern United States might destroy it over time. You take samples of granite, marble, bronze, and other materials, and place them outdoors for a long time in the big city. You periodically examine the appearance and measure the mass of the samples. (a) What observations would lead you to conclude that one or more of the materials are well- suited for the sculpture?

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Textbook Question

You are working with an artist who has been commissioned to make a sculpture for a big city in the eastern United States. The artist is wondering what material to use to make her sculpture because she has heard that acid rain in the eastern United States might destroy it over time. You take samples of granite, marble, bronze, and other materials, and place them outdoors for a long time in the big city. You periodically examine the appearance and measure the mass of the samples. (b) What chemical process (or processes) is (are) the most likely responsible for any observed changes in the materials? [Section 18.2]

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