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Ch 18: Thermal Properties of Matter
Young & Freedman Calc - University Physics 14th Edition
Young & Freedman Calc14th EditionUniversity PhysicsISBN: 9780321973610Not the one you use?Change textbook
Chapter 18, Problem 6a

You have several identical balloons. You experimentally determine that a balloon will break if its volume exceeds 0.9000.900 L. The pressure of the gas inside the balloon equals air pressure (1.001.00 atm). If the air inside the balloon is at a constant 22.022.0°C and behaves as an ideal gas, what mass of air can you blow into one of the balloons before it bursts?

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First, understand that the problem involves the ideal gas law, which is given by the equation: PV=nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin.
Convert the given temperature from Celsius to Kelvin using the formula: Tk=Tc+273.15. For 22.0°C, this becomes 22.0+273.15.
Substitute the known values into the ideal gas law equation. Use P=1.00 atm, V=0.900 L, and the converted temperature in Kelvin. The ideal gas constant R is 0.0821 L atm mol-1 K-1.
Solve for the number of moles n using the rearranged ideal gas law: n=PVRT.
Finally, convert the number of moles to mass. Use the molar mass of air, which is approximately 28.97 g mol-1. Multiply the number of moles by the molar mass to find the mass of air that can be blown into the balloon before it bursts.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Ideal Gas Law

The Ideal Gas Law is a fundamental equation in physics that relates the pressure, volume, temperature, and number of moles of an ideal gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law helps determine the amount of gas that can be added to a balloon before it bursts.
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Conversion of Temperature to Kelvin

In gas law calculations, temperature must be expressed in Kelvin. To convert from Celsius to Kelvin, add 273.15 to the Celsius temperature. For this problem, the given temperature is 22.0°C, which converts to 295.15 K. This conversion is crucial for accurately applying the Ideal Gas Law.
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Molar Mass of Air

The molar mass of air is an average value based on the composition of gases in the atmosphere, primarily nitrogen and oxygen. It is approximately 28.97 g/mol. Knowing the molar mass allows us to convert between the number of moles and the mass of air, which is necessary to find out how much air can be added to the balloon before it bursts.
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Related Practice
Textbook Question

Helium gas with a volume of 3.203.20 L, under a pressure of 0.1800.180 atm and at 41.041.0°C, is warmed until both pressure and volume are doubled. How many grams of helium are there? The molar mass of helium is 4.004.00 g/mol.

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Textbook Question

A cylindrical tank has a tight-fitting piston that allows the volume of the tank to be changed. The tank originally contains 0.1100.110 m3 of air at a pressure of 0.3550.355 atm. The piston is slowly pulled out until the volume of the gas is increased to 0.3900.390 m3. If the temperature remains constant, what is the final value of the pressure?

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Textbook Question

Calculate the density of the atmosphere at the surface of Mars (where the pressure is 650650 Pa and the temperature is typically 253253 K, with a CO2 atmosphere), Venus (with an average temperature of 730730 K and pressure of 9292 atm, with a CO2 atmosphere), and Saturn's moon Titan (where the pressure is 1.51.5 atm and the temperature is 178-178°C, with a N2 atmosphere).

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Textbook Question

A large cylindrical tank contains 0.7500.750 m3 of nitrogen gas at 2727°C and 7.50×1037.50\times10^3 Pa (absolute pressure). The tank has a tight-fitting piston that allows the volume to be changed. What will be the pressure if the volume is decreased to 0.4100.410 m3 and the temperature is increased to 157157°C?

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Textbook Question

If a certain amount of ideal gas occupies a volume V at STP on earth, what would be its volume (in terms of V) on Venus, where the temperature is 10031003°C and the pressure is 9292 atm?

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Textbook Question

Martian Climate. The atmosphere of Mars is mostly CO2 (molar mass 44.0 g/mol) under a pressure of 650 Pa, which we shall assume remains constant. In many places the temperature varies from 0.0°C in summer to -100°C in winter. Over the course of a Martian year, what are the ranges of (b) the density (in mol/m^3) of the atmosphere?

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