As the intermolecular attractive forces between molecules increase in magnitude, do you expect each of the following to increase or decrease in magnitude? (g) critical temperature.
Ch.11 - Liquids and Intermolecular Forces
Chapter 11, Problem 74b
The table below lists the density of O2 at various temperatures and at 1 atm. The normal melting point of O2 is 54 K.
(b) Over what temperature range is O2 a liquid?

1
Determine the phase change temperatures for O_2. The normal melting point is given as 54 K, which is the temperature at which O_2 transitions from solid to liquid.
Identify the boiling point of O_2 at 1 atm. This is the temperature at which O_2 transitions from liquid to gas. You may need to look up this value if it's not provided in the problem.
Understand that O_2 will be in the liquid phase between its melting point and boiling point.
Express the temperature range for the liquid phase of O_2 as the interval between the melting point and boiling point.
Conclude that O_2 is a liquid between the melting point (54 K) and the boiling point (which you need to find).

Verified video answer for a similar problem:
This video solution was recommended by our tutors as helpful for the problem above.
Video duration:
55sWas this helpful?
Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Phase Changes
Phase changes refer to the transitions between solid, liquid, and gas states of matter. For oxygen (O2), understanding these changes is crucial, particularly the melting point and boiling point, which define the temperature ranges where the substance exists as a solid, liquid, or gas. The melting point indicates the temperature at which O2 transitions from solid to liquid, while the boiling point marks the change from liquid to gas.
Recommended video:
Guided course
Entropy in Phase Changes
Density and Temperature Relationship
Density is defined as mass per unit volume and can vary with temperature. For gases like O2, density decreases as temperature increases, due to the increased kinetic energy of the molecules causing them to occupy more space. This relationship is important for determining the state of a substance at different temperatures, particularly when assessing whether O2 is in a liquid state at specific temperatures.
Recommended video:
Guided course
Temperature vs Heat
Critical Point
The critical point of a substance is the temperature and pressure at which the distinction between liquid and gas phases disappears. For O2, knowing the critical temperature helps in understanding the conditions under which it can exist as a liquid. If the temperature is below the critical temperature and above the melting point, O2 can exist as a liquid, which is essential for answering the question about its liquid state.
Recommended video:
Guided course
Boiling Point Elevation
Related Practice
Textbook Question
669
views
Textbook Question
Suppose you have two colorless molecular liquids, one boiling at - 84 °C, the other at 34 °C, and both at atmospheric 6 pressure. Which of the following statements is correct? For each statement that is not correct, modify the statement so that it is correct. (d) The two liquids have identical vapor pressures at their normal boiling points.
668
views
Textbook Question
Suppose you have two colorless molecular liquids, one boiling at - 84 °C, the other at 34 °C, and both at atmospheric 6 pressure. Which of the following statements is correct? For each statement that is not correct, modify the statement so that it is correct. (e) At - 84 °C both liquids have vapor pressures of 760 mm Hg.
478
views