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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 82d

(d) If 42.7 mL of 0.208 M HCl solution is needed to neutralize a solution of Ca(OH)2, how many grams of Ca(OH)2 must be in the solution?

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Start by writing the balanced chemical equation for the neutralization reaction between HCl and Ca(OH)2: Ca(OH)2(aq)+2HCl(aq)CaCl(aq)2+2H(OH)(l).
Calculate the moles of HCl used in the reaction. Use the formula: moles=volume×molarity. Convert the volume from mL to L by dividing by 1000.
Using the stoichiometry from the balanced equation, determine the moles of Ca(OH)2 that reacted. According to the equation, 2 moles of HCl react with 1 mole of Ca(OH)2. Therefore, divide the moles of HCl by 2 to find the moles of Ca(OH)2.
Calculate the mass of Ca(OH)2 using its molar mass. The molar mass of Ca(OH)2 is the sum of the atomic masses of Ca, O, and H: molar mass=40.08+2×(16.00+1.01). Multiply the moles of Ca(OH)2 by its molar mass to find the mass in grams.
Ensure all units are consistent and check your calculations for accuracy. This will give you the mass of Ca(OH)2 required to neutralize the given amount of HCl.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Neutralization Reaction

A neutralization reaction occurs when an acid reacts with a base to produce water and a salt. In this case, hydrochloric acid (HCl) reacts with calcium hydroxide (Ca(OH)2). The balanced chemical equation for this reaction is 2 HCl + Ca(OH)2 → CaCl2 + 2 H2O, indicating that two moles of HCl are required to neutralize one mole of Ca(OH)2.
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Molarity and Volume Relationship

Molarity (M) is defined as the number of moles of solute per liter of solution. To find the number of moles of HCl used in the reaction, you can use the formula: moles = molarity × volume (in liters). In this problem, the volume of HCl is given in milliliters, so it must be converted to liters before calculating the moles.
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Stoichiometry

Stoichiometry involves using the coefficients from a balanced chemical equation to relate the amounts of reactants and products. In this case, knowing the moles of HCl allows you to determine the moles of Ca(OH)2 that reacted, and subsequently, you can convert moles of Ca(OH)2 to grams using its molar mass. This is essential for solving the problem accurately.
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