List the individual steps used in constructing a Born–Haber cycle for the formation of BaI2 from the elements. Which of the steps would you expect to be exothermic?
(a) State whether or not the bonding in each substance is likely to be covalent: (i) glucose, (ii) nitrogen, (iii) aluminum hydroxide, (iv) ammonia, (v) neon.
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Covalent Bonding
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Electronegativity
(a) Based on the lattice energies of MgCl2 and SrCl2 given in Table 8.1, what is the range of values that you would expect for the lattice energy of CaCl2?
(b) Using data from Appendix C, Figure 7.11, Figure 7.13, and the value of the second ionization energy for Ca, 1145 kJ/mol, calculate the lattice energy of CaCl2.
(b) A substance, XY, formed from two different elements, melts at −33 °C. Is XY likely to be a covalent or an ionic substance?
Using Lewis symbols and Lewis structures, make a sketch of the formation of NCl3 from N and Cl atoms, showing valence-shell electrons. (a) How many valence electrons does N have initially? (c) How many valence electrons surround the N in the NCl3 molecule? (d) How many valence electrons surround each Cl in the NCl3 molecule?
