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Ch.17 - Additional Aspects of Aqueous Equilibria
Chapter 17, Problem 6a

Match the following descriptions of titration curves with the diagrams: (a) strong acid added to strong base. [Section 17.3]

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1
Identify the characteristics of a titration curve for a strong acid added to a strong base.
Recall that the equivalence point for a strong acid-strong base titration occurs at a pH of 7.
Understand that the initial pH of the solution will be high because it starts with a strong base.
As the strong acid is added, the pH will decrease gradually until it reaches the equivalence point.
After the equivalence point, the pH will decrease more rapidly as excess strong acid is added.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Titration Curves

Titration curves graphically represent the pH changes that occur during the titration process. They plot the volume of titrant added against the pH of the solution, illustrating how the acidity or basicity of the solution changes as the titrant is added. Understanding these curves is essential for interpreting the neutralization point and the strength of the acids and bases involved.
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Acid-Base Titration Curves

Strong Acid and Strong Base

A strong acid completely dissociates in solution, releasing all of its hydrogen ions (H+), while a strong base completely dissociates to release hydroxide ions (OH-). When titrating a strong acid with a strong base, the resulting titration curve typically shows a sharp increase in pH at the equivalence point, where the amount of acid equals the amount of base, leading to a neutral solution.
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Strong Acid-Strong Base Titration

Equivalence Point

The equivalence point in a titration is the stage at which the amount of titrant added is stoichiometrically equivalent to the amount of substance being titrated. For a strong acid-strong base titration, this point is characterized by a rapid change in pH, typically occurring around pH 7. Understanding the equivalence point is crucial for determining the concentration of the unknown solution.
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At the Equivalence Point