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Ch.10 Acids and Bases and Equilibrium
Timberlake - Chemistry: An Introduction to General, Organic, and Biological Chemistry 13th Edition
Timberlake13th EditionChemistry: An Introduction to General, Organic, and Biological ChemistryISBN: 9780134421353Not the one you use?Change textbook
Chapter 10, Problem 112c

The daily output of stomach acid (gastric juice) is 1000 mL to 2000 mL. Prior to a meal, stomach acid (HCl) typically has a pH of 1.42.
c. The antacid milk of magnesia contains 400. mg of Mg(OH)2 per teaspoon. Write the neutralization equation, and calculate the number of milliliters of stomach acid neutralized by 1 tablespoon of milk of magnesia (1tablespoon = 3teaspoons).

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1
Step 1: Write the balanced neutralization equation. Magnesium hydroxide (Mg(OH)₂) reacts with hydrochloric acid (HCl) in a 1:2 molar ratio to form magnesium chloride (MgCl₂) and water (H₂O). The balanced equation is: Mg(OH)₂ + 2HCl → MgCl₂ + 2H₂O.
Step 2: Determine the mass of Mg(OH)₂ in 1 tablespoon of milk of magnesia. Since 1 tablespoon equals 3 teaspoons, and each teaspoon contains 400 mg of Mg(OH)₂, the total mass of Mg(OH)₂ in 1 tablespoon is: 400 mg × 3 = 1200 mg (or 1.2 g).
Step 3: Convert the mass of Mg(OH)₂ to moles. Use the molar mass of Mg(OH)₂ (24.31 g/mol for Mg, 16.00 g/mol for O, and 1.01 g/mol for H): Molar mass of Mg(OH)₂ = 24.31 + (2 × (16.00 + 1.01)) = 58.32 g/mol. Then, calculate the moles of Mg(OH)₂: moles = mass (g) / molar mass (g/mol).
Step 4: Use the stoichiometry of the reaction to determine the moles of HCl neutralized. From the balanced equation, 1 mole of Mg(OH)₂ reacts with 2 moles of HCl. Multiply the moles of Mg(OH)₂ by 2 to find the moles of HCl neutralized.
Step 5: Calculate the volume of stomach acid neutralized. The concentration of HCl in stomach acid can be determined from its pH (pH = -log[H⁺], so [H⁺] = 10^(-pH)). Use the moles of HCl neutralized and the concentration of HCl to calculate the volume of stomach acid neutralized: volume (L) = moles of HCl / concentration of HCl. Convert the volume to milliliters (1 L = 1000 mL).

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Neutralization Reaction

A neutralization reaction occurs when an acid reacts with a base to produce water and a salt. In this context, the stomach acid (HCl) reacts with magnesium hydroxide (Mg(OH)₂) from milk of magnesia. The general equation for this reaction is: HCl + Mg(OH)₂ → MgCl₂ + 2H₂O. Understanding this reaction is crucial for calculating how much stomach acid can be neutralized by the antacid.
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Molarity and Concentration

Molarity is a measure of the concentration of a solute in a solution, expressed in moles per liter (mol/L). To calculate how much stomach acid is neutralized, one must know the concentration of HCl in the stomach and the amount of Mg(OH)₂ in the milk of magnesia. This concept is essential for determining the stoichiometric relationships in the neutralization reaction.
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Volume Calculation

Volume calculation involves determining the amount of space that a substance occupies, often measured in milliliters (mL). In this problem, it is necessary to calculate the volume of stomach acid neutralized by a specific volume of milk of magnesia. This requires using the molarity of the acid and the amount of base to find the resulting volume of neutralized acid.
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