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Ch.3 - Chemical Reactions and Reaction Stoichiometry
Chapter 3, Problem 45b

Give the empirical formula of each of the following compounds if a sample contains (b) 2.10 g nickel and 0.58 g oxygen

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Step 1: The first step in determining the empirical formula of a compound is to convert the mass of each element to moles. This is done by dividing the given mass of each element by its atomic mass. The atomic mass of nickel (Ni) is approximately 58.69 g/mol and the atomic mass of oxygen (O) is approximately 16.00 g/mol.
Step 2: After converting the masses to moles, you will have the mole ratio of the elements in the compound. However, this ratio may not be in the simplest whole number form. To find the simplest whole number ratio, divide each value by the smallest number of moles calculated in the previous step.
Step 3: If the mole ratio obtained in the previous step is not a whole number, it may be necessary to multiply each value by a factor (such as 2, 3, etc.) to obtain whole numbers. This is often the case when dealing with elements that tend to form multiple bonds, like oxygen.
Step 4: Once you have the simplest whole number ratio of moles for each element, you can write the empirical formula. The empirical formula is written by listing the elements in the same order as in the original compound formula, followed by the number of atoms of each in subscript (if more than one).
Step 5: It's important to note that the empirical formula does not provide information about the actual number of atoms in a molecule of the compound, it only gives the simplest whole number ratio of atoms. The molecular formula may be a multiple of the empirical formula.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Empirical Formula

The empirical formula of a compound represents the simplest whole-number ratio of the elements present in that compound. It is derived from the mass of each element in a sample and is crucial for understanding the composition of the substance. For example, if a compound contains elements A and B in a 1:2 ratio, its empirical formula would be AB2.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is essential for converting the mass of an element in a sample to the number of moles, which is necessary for determining the empirical formula. For instance, the molar mass of nickel (Ni) is approximately 58.69 g/mol, and for oxygen (O), it is about 16.00 g/mol.
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Stoichiometry

Stoichiometry is the branch of chemistry that deals with the quantitative relationships between the reactants and products in a chemical reaction. It allows chemists to calculate the amounts of substances involved based on their molar ratios. In the context of finding an empirical formula, stoichiometry helps in determining the mole ratio of the elements from their masses, which is fundamental for deriving the empirical formula.
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