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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 91a,b

Uranium hexafluoride, UF6, is processed to produce fuel for nuclear reactors and nuclear weapons. UF6 can be produced in a two-step reaction. Solid uranium (IV) oxide, UO2, is first made to react with hydrofluoric acid (HF) solution to form solid UF4 with water as a by-product. UF4 further reacts with fluorine gas to form UF6. (a) Write the balanced molecular equations for the conversion of UO2 into UF4 and the conversion of UF4 to UF6. (b) Which step is an acid-base reaction?

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insert step 1> Identify the two reactions involved in the production of UF6.
insert step 2> Write the balanced chemical equation for the first reaction: UO2 + HF -> UF4 + H2O.
insert step 3> Recognize that an acid-base reaction involves the transfer of protons (H+ ions) from an acid to a base.
insert step 4> Analyze the first reaction: Hydrofluoric acid (HF) donates a proton to form water (H2O), indicating an acid-base reaction.
insert step 5> Conclude that the first step, where UO2 reacts with HF, is the acid-base reaction.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Acid-Base Reactions

Acid-base reactions involve the transfer of protons (H+) between reactants. In these reactions, an acid donates a proton, while a base accepts it. Understanding this concept is crucial for identifying which step in a chemical process qualifies as an acid-base reaction, as it helps to determine the roles of the reactants involved.
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Uranium Compounds

Uranium compounds, such as uranium(IV) oxide (UO2) and uranium tetrafluoride (UF4), are important in nuclear chemistry. UO2 is a common form of uranium used in nuclear fuel, while UF4 is an intermediate in the production of uranium hexafluoride (UF6). Recognizing the properties and reactions of these compounds is essential for understanding the overall process of uranium processing.
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Fluorine Chemistry

Fluorine is a highly reactive halogen that readily forms compounds with metals and nonmetals. In the context of the given reaction, fluorine gas reacts with UF4 to produce UF6. Understanding fluorine's reactivity and its role in forming stable compounds is key to analyzing the second step of the reaction and its significance in nuclear fuel production.
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Related Practice
Textbook Question

A solution is made by mixing 1.5 g of Sr(OH)2 and 23.5 mL of 1.000 M HNO3. (c) Is the resulting solution acidic or basic?

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Textbook Question

A 0.5895-g sample of impure magnesium hydroxide is dissolved in 100.0 mL of 0.2050 M HCl solution. The excess acid then needs 19.85 mL of 0.1020 M NaOH for neutralization. Calculate the percentage by mass of magnesium hydroxide in the sample, assuming that it is the only substance reacting with the HCl solution.

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Textbook Question

A 1.248-g sample of limestone rock is pulverized and then treated with 30.00 mL of 1.035 M HCl solution. The excess acid then requires 11.56 mL of 1.010 M NaOH for neutralization. Calculate the percentage by mass of calcium carbonate in the rock, assuming that it is the only substance reacting with the HCl solution.

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Textbook Question

The accompanying photo shows the reaction between a solution of Cd(NO3)2 and one of Na2S. (b) What ions remain in solution?

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Textbook Question

The accompanying photo shows the reaction between a solution of Cd(NO3)2 and one of Na2S. (d) Is this a redox reaction?

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Open Question
Suppose you have a solution that might contain any or all of the following cations: Ni2+, Ag+, Sr2+, and Mn2+. Addition of HCl solution causes a precipitate to form. After filtering off the precipitate, H2SO4 solution is added to the resulting solution and another precipitate forms. This is filtered off, and a solution of NaOH is added to the resulting solution. No precipitate is observed. Which of the four ions listed above must be absent from the original solution?