Table of contents
- 1. The Chemical World9m
- 2. Measurement and Problem Solving2h 19m
- 3. Matter and Energy2h 15m
- Classification of Matter18m
- States of Matter8m
- Physical & Chemical Changes19m
- Chemical Properties8m
- Physical Properties5m
- Temperature (Simplified)9m
- Law of Conservation of Mass5m
- Nature of Energy5m
- First Law of Thermodynamics7m
- Endothermic & Exothermic Reactions7m
- Heat Capacity17m
- Thermal Equilibrium (Simplified)8m
- Intensive vs. Extensive Properties13m
- 4. Atoms and Elements2h 33m
- The Atom (Simplified)9m
- Subatomic Particles (Simplified)11m
- Isotopes17m
- Ions (Simplified)22m
- Atomic Mass (Simplified)17m
- Periodic Table: Element Symbols6m
- Periodic Table: Classifications11m
- Periodic Table: Group Names8m
- Periodic Table: Representative Elements & Transition Metals7m
- Periodic Table: Phases (Simplified)8m
- Periodic Table: Main Group Element Charges12m
- Atomic Theory9m
- Rutherford Gold Foil Experiment9m
- 5. Molecules and Compounds1h 50m
- Law of Definite Proportions9m
- Periodic Table: Elemental Forms (Simplified)6m
- Naming Monoatomic Cations6m
- Naming Monoatomic Anions5m
- Polyatomic Ions25m
- Naming Ionic Compounds11m
- Writing Formula Units of Ionic Compounds7m
- Naming Acids18m
- Naming Binary Molecular Compounds6m
- Molecular Models4m
- Calculating Molar Mass9m
- 6. Chemical Composition1h 23m
- 7. Chemical Reactions1h 43m
- 8. Quantities in Chemical Reactions1h 8m
- 9. Electrons in Atoms and the Periodic Table2h 32m
- Wavelength and Frequency (Simplified)5m
- Electromagnetic Spectrum (Simplified)11m
- Bohr Model (Simplified)9m
- Emission Spectrum (Simplified)3m
- Electronic Structure4m
- Electronic Structure: Shells5m
- Electronic Structure: Subshells4m
- Electronic Structure: Orbitals11m
- Electronic Structure: Electron Spin3m
- Electronic Structure: Number of Electrons4m
- The Electron Configuration (Simplified)20m
- The Electron Configuration: Condensed4m
- Ions and the Octet Rule9m
- Valence Electrons of Elements (Simplified)5m
- Periodic Trend: Metallic Character4m
- Periodic Trend: Atomic Radius (Simplified)7m
- Periodic Trend: Ionization Energy (Simplified)9m
- Periodic Trend: Electron Affinity (Simplified)7m
- Electron Arrangements5m
- The Electron Configuration: Exceptions (Simplified)12m
- 10. Chemical Bonding2h 10m
- Lewis Dot Symbols (Simplified)7m
- Ionic Bonding6m
- Covalent Bonds6m
- Lewis Dot Structures: Neutral Compounds (Simplified)8m
- Bonding Preferences6m
- Multiple Bonds4m
- Lewis Dot Structures: Multiple Bonds10m
- Lewis Dot Structures: Ions (Simplified)8m
- Lewis Dot Structures: Exceptions (Simplified)12m
- Resonance Structures (Simplified)5m
- Valence Shell Electron Pair Repulsion Theory (Simplified)4m
- Electron Geometry (Simplified)7m
- Molecular Geometry (Simplified)9m
- Bond Angles (Simplified)11m
- Dipole Moment (Simplified)14m
- Molecular Polarity (Simplified)7m
- 11 Gases2h 7m
- 12. Liquids, Solids, and Intermolecular Forces1h 11m
- 13. Solutions3h 1m
- 14. Acids and Bases2h 14m
- 15. Chemical Equilibrium1h 27m
- 16. Oxidation and Reduction1h 33m
- 17. Radioactivity and Nuclear Chemistry53m
13. Solutions
The Colligative Properties
Problem 22
Textbook Question
The diagram to the right shows plots of vapor pressure versus temperature for a solvent and a solution. What is the approximate boiling-point elevation for the solution?

1
Identify the boiling point of the pure solvent from the vapor pressure versus temperature plot. This is the temperature at which the vapor pressure of the solvent equals the atmospheric pressure.
Identify the boiling point of the solution from the same plot. This is the temperature at which the vapor pressure of the solution equals the atmospheric pressure.
Calculate the boiling-point elevation by subtracting the boiling point of the pure solvent from the boiling point of the solution.
Recall that boiling-point elevation is a colligative property, which means it depends on the number of solute particles in the solution, not their identity.
Use the formula for boiling-point elevation, \( \Delta T_b = i \cdot K_b \cdot m \), where \( \Delta T_b \) is the boiling-point elevation, \( i \) is the van't Hoff factor, \( K_b \) is the ebullioscopic constant, and \( m \) is the molality of the solution, to understand the factors affecting the elevation.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Vapor Pressure
Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid phase at a given temperature. It reflects the tendency of particles to escape from the liquid phase into the vapor phase. As temperature increases, vapor pressure also increases, which is crucial for understanding boiling points.
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Boiling Point Elevation
Boiling point elevation is a colligative property that describes the increase in the boiling point of a solvent when a solute is dissolved in it. This phenomenon occurs because the presence of solute particles disrupts the formation of vapor above the liquid, requiring a higher temperature to reach the vapor pressure equal to atmospheric pressure.
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Colligative Properties
Colligative properties are properties of solutions that depend on the number of solute particles in a given amount of solvent, rather than the identity of the solute. These properties include boiling point elevation, freezing point depression, vapor pressure lowering, and osmotic pressure, and they are essential for understanding how solutes affect the physical properties of solvents.
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