18. Aqueous Equilibrium

Chemistry student is using an indicator with a pK_a of 4.7 for the titration of a strong acid with strong base. Calculate the pH range at which the indicator will change colors.

a) 2.7–3.5                      b) 10–11                        c) 4.7–8.7                      d) 3.7–5.7                      e) 2.7–5.8

Bromophenol blue (pK_a = 4.1) is a common acid-base indicator. It is yellow in its acidic form and blue in conjugate base form. If the solution being titrated has a pH = 4.0, what color would the bromophenol blue indicator possess?

a) yellow                       b) orange                      c) blue                          d) green                      e) purple 

The beaker on the right contains 0.1 M acetic acid solution with methyl orange as an indicator. The beaker on the left contains a mixture of 0.1 M acetic acid and 0.1 M sodium acetate with methyl orange. (a) Using Figures 16.8 and 16.9, which solution has a higher pH?

The indicator methyl orange has been added to both of the following solutions. Based on the colors, classify each statement as true or false: (a) The pH of solution A is definitely less than 7.00. (b) The pH of solution B is definitely greater than 7.00. (c) The pH of solution B is greater than that of solution A.

You are titrating an acidic solution with a basic one, and just realized you forgot to add the indicator that tells you when the equivalence point is reached. In this titration, the indicator turns blue at the equivalence point from an initially colorless solution. You quickly grab a bottle of indicator and add some to your titration beaker, and the whole solution turns dark blue. What do you do now?

Addition of the indicator methyl orange to an unknown solution leads to a yellow color. The addition of bromthymol blue to the same solution also leads to a yellow color. (b) What is the range (in whole numbers) of possible pH values for the solution?