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Multiple Choice
Given the following standard reduction potentials:A^{2+} + 2e^- → A(s)E^ext{°} = -0.50ext{ V}B^{+} + e^- → B(s)E^ext{°} = +0.20ext{ V}Which species is the stronger oxidizing agent under standard conditions?
A
A^{2+}
B
B(s)
C
B^{+}
D
A(s)
Verified step by step guidance
1
Recall that the strength of an oxidizing agent is related to its tendency to gain electrons, which corresponds to the standard reduction potential (E^{\circ}). The species with the higher (more positive) standard reduction potential is the stronger oxidizing agent.
Identify the given half-reactions and their standard reduction potentials:
\(A^{2+} + 2e^- \rightarrow A(s) \quad E^{\circ} = -0.50\ \text{V}\)
\(B^{+} + e^- \rightarrow B(s) \quad E^{\circ} = +0.20\ \text{V}\)
Compare the standard reduction potentials: since \(+0.20\ \text{V} > -0.50\ \text{V}\), the species \(B^{+}\) has a higher tendency to be reduced (gain electrons) than \(A^{2+}\).
Because the oxidizing agent is the species that gets reduced, the stronger oxidizing agent under standard conditions is the one with the higher reduction potential, which is \(B^{+}\).
Therefore, among the options given, \(B^{+}\) is the stronger oxidizing agent.