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Multiple Choice
Which of the following molecules would have the highest boiling point?
A
H_2O
B
CH_4
C
CO_2
D
NH_3
Verified step by step guidance
1
Step 1: Understand that boiling point is influenced by the strength of intermolecular forces present in the substance. Stronger intermolecular forces result in higher boiling points because more energy is required to separate the molecules.
Step 2: Identify the types of intermolecular forces in each molecule: CH_4 (methane) and CO_2 (carbon dioxide) are nonpolar molecules and primarily exhibit London dispersion forces, which are relatively weak.
Step 3: NH_3 (ammonia) is a polar molecule and exhibits hydrogen bonding due to the presence of N-H bonds, which is a stronger intermolecular force than dispersion forces.
Step 4: H_2O (water) is also polar and exhibits hydrogen bonding, but the hydrogen bonding in water is generally stronger than in ammonia because oxygen is more electronegative than nitrogen, leading to stronger dipole interactions.
Step 5: Conclude that since H_2O has the strongest hydrogen bonding among the given molecules, it will have the highest boiling point.