24. Transition Metals and Coordination Compounds

Coordination Isomers

Structural Isomerism in Coordination Compounds | Types: Linkage, Coordination, Ionization, Hydrate

23.4.2 Isomers Overview

Isomerism in Coordination Compounds - Coordination chemistry

Structural Isomerism

The ligands coordinate to the metal in different ways.

The ligands have different spatial arrangements about the metal ion.

Atoms have the same connectivity, but different spatial arrangements.

The ligands and counterions exchange places.

Correct description of coordination isomers.

The compounds are nonsuperimposable mirror images.

 Review the definition of coordination isomers found in Section 26.4. 

Which of the following is true for coordination isomers?

Linkage & Coordination Isomerism| Part -18| Unit 9| Cbse grade 12 chemistry|by Vani ma'am

23.4.4 Coordination Sphere Isomers

Think about the number that the term tetra references.

(NH4)2[CuCl4]

Correct formulation of the formula from the name.

Recall that this compound is electrically neutral.

(NH4)2[CuCl2]

 Review the rules for naming coordination compounds found in Section 26.3. 

Write the formula for the coordination compound that is named as ammonium tetrachlorocuprate(II).

Isomers of Transition Metal Complexes

This complex ion does have stereoisomers.

Correct, this ion can exist are cis and trans isomers.

Due to the geometry of this ion, fac and mer isomers are not possible.

Consider that this is a square planar complex.

 Begin by determining the geometry of the complex ion. 

How many stereoisomers are possible for Ni(NH3)2Br2?

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