What is each compound's systematic name? a. CH3C☰CCH2CH2CH2CH═CH2
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Step 1: Identify the longest continuous carbon chain in the molecule. This chain will determine the base name of the compound. Count the number of carbons in the chain, ensuring it includes both the triple bond (alkyne) and the double bond (alkene).
Step 2: Assign priority to the functional groups. In this case, the triple bond (alkyne) and the double bond (alkene) are both present. The double bond takes precedence in numbering the chain, so start numbering from the end closest to the double bond.
Step 3: Determine the position of the triple bond and the double bond within the chain. Use the numbering system established in Step 2 to assign the lowest possible numbers to these bonds. For example, the double bond might be at position 7, and the triple bond at position 2.
Step 4: Combine the names of the functional groups with the base name of the chain. Use the suffix '-yne' for the triple bond and '-ene' for the double bond, and include their positions in the name. For example, the name might include 'hept-7-ene-2-yne' to indicate the positions of the double and triple bonds.
Step 5: Add any substituents to the name. Identify and name any groups attached to the main chain, such as methyl groups. Include their positions in the name, ensuring the numbering is consistent with the priority rules. For example, '3-methyl' might be added to the name if a methyl group is attached at position 3.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
IUPAC Nomenclature
IUPAC nomenclature is a systematic method for naming organic chemical compounds. It provides rules for naming based on the structure of the molecule, including the longest carbon chain, functional groups, and the position of double or triple bonds. Understanding these rules is essential for accurately determining the systematic name of a compound.
Alkenes and alkynes are types of unsaturated hydrocarbons characterized by the presence of double and triple bonds, respectively. Alkenes contain at least one carbon-carbon double bond (C=C), while alkynes have at least one carbon-carbon triple bond (C≡C). Recognizing these functional groups is crucial for naming compounds and understanding their reactivity.
The chain length of a hydrocarbon refers to the number of carbon atoms in the longest continuous chain. Substituents are groups attached to this chain that can influence the compound's name and properties. Identifying the main chain and any substituents is vital for applying IUPAC rules to derive the correct systematic name.